Zobrazeno 1 - 10
of 78
pro vyhledávání: '"Zbigniew Grobelny"'
Publikováno v:
eXPRESS Polymer Letters, Vol 16, Iss 5, Pp 465-475 (2022)
Various potassium salts, i.e., KOH, HOC3H6OC3H6OK, CH3OK, i-PrOK, t-BuOK, CbK, and (Me3Si)2NK activated by 18-crown-6 appeared to be active initiators of first anionic polymerization of isobutylene oxide. The processes were performed in mild conditio
Externí odkaz:
https://doaj.org/article/487e548996254692859aa14407908baf
Publikováno v:
Polymer Bulletin. 80:6307-6326
Publikováno v:
Journal of Decision Systems. 29:301-311
Autor:
Zbigniew Grobelny, Andrzej Swinarew, Justyna Jurek-Suliga, Kinga Skrzeczyna, Jadwiga Gabor, Marta Łężniak
Publikováno v:
International Journal of Analytical Chemistry, Vol 2016 (2016)
Potassium t-butoxide dissolved in tetrahydrofuran effectively initiates homogeneous polymerization of propylene oxide at room temperature. Unsaturation and molar mass (Mn) of the polymers prepared depend on the presence of additives, such as macrocyc
Externí odkaz:
https://doaj.org/article/f8f07e8c0a0844408b10c8c67ce5b7a7
Publikováno v:
Polymer Bulletin. 76:6291-6303
Several new random copolyethers of styrene oxide (SO) and other monosubstituted oxirane as comonomer, i.e., propylene oxide (PO), isopropyl glycidyl ether (IPGE) or allyl glycidyl ether (AGE), were synthesized in THF solution at room temperature. As
Publikováno v:
Polymers
Volume 13
Issue 13
Polymers, Vol 13, Iss 2150, p 2150 (2021)
Volume 13
Issue 13
Polymers, Vol 13, Iss 2150, p 2150 (2021)
Polyether-pentols (PEPOs) were synthesized from glycidyl ethers and butylene oxide with the application of tripotassium salts of 2,2,6,6-tetrakis(hydroxymethyl)cyclohexanol (HMCH) activated 18C6 for ring-opening polymerization (ROP). The construction
Publikováno v:
Polymer Bulletin. 76:4951-4966
Several alkali metal salts that activated 18-crown-6 were applied as initiators of β-butyrolactone anionic ring-opening polymerization in tetrahydrofuran at room temperature. Some of them, i.e., Ph2PK, Ph3HBK, ( Me3Si)2NK, and t-BuOK, deprotonate th
Publikováno v:
Iranian Polymer Journal. 27:745-754
Application of novel potassium salts (from mono- to penta-potassium) of 2,2,6,6-tetrakis(hydroxymethyl) cyclohexanol-activated 18C6 for propylene oxide polymerization is investigated. The novelty of the research concerns utilization of the cyclic-str
Autor:
Aneta Chrząszcz, Zbigniew Grobelny
Publikováno v:
Współczesne Problemy Zarządzania. 6:117-128
Bezpieczeństwo energetyczne to odporność gospodarki na możliwe zakłócenia w sferze pokrycia bieżącego i perspektywicznego zapotrzebowania odbiorców na paliwa i energię, przy zachowaniu wymagań technicznych i ekonomicznych oraz ochrony śro
Publikováno v:
Polymer Bulletin. 75:1101-1121
Anionic polymerization of propylene oxide was carried out in the presence of two groups of potassium salts activated 18-crown-6 (18C6), e.g. alkoxide salts (CH3OK, i-PrOK, t-BuOK, CH3OCH2CH(CH3)OK, KCH2O) and other salts (CbK, Ph3CK, Ph2PK, Ph3HBK, K