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Configurationally Nonselective Aquation of a Mononuclear Ru(II) Chloro Complex to Aquo Complex Isomers with Distinctive Aspects in Photoisomerization, Redox, and Catalytic Water Oxidation.

Autor: Tsubonouchi Y; Department of Materials Science and Technology, Faculty of Engineering, Niigata University, 8050 Ikarashi-2, Niigata 950-2181, Japan., Inaba K; Department of Materials Science and Technology, Faculty of Engineering, Niigata University, 8050 Ikarashi-2, Niigata 950-2181, Japan., Hoshino N; Department of Materials Science and Technology, Faculty of Engineering, Niigata University, 8050 Ikarashi-2, Niigata 950-2181, Japan., Hirahara M; Department of Applied Chemistry, Osaka Institute of Technology, 5-16-1 Omiya, Asahi-ku, Osaka 535-8585, Japan., Chandra D; Department of Materials Science and Technology, Faculty of Engineering, Niigata University, 8050 Ikarashi-2, Niigata 950-2181, Japan., Zahran ZN; Department of Materials Science and Technology, Faculty of Engineering, Niigata University, 8050 Ikarashi-2, Niigata 950-2181, Japan., Yagi M; Department of Materials Science and Technology, Faculty of Engineering, Niigata University, 8050 Ikarashi-2, Niigata 950-2181, Japan.

Publikováno v: Inorganic chemistry [Inorg Chem] 2023 Oct 30; Vol. 62 (43), pp. 17654-17667. Date of Electronic Publication: 2023 Oct 18.

Distinctive Aspects in Aquation, Proton-Coupled Redox, and Photoisomerization Reactions between Geometric Isomers of Mononuclear Ruthenium Complexes with a Large-π-Conjugated Tetradentate Ligand.

Autor: Tsubonouchi Y; Department of Materials Science and Technology, Faculty of Engineering, Niigata University, 8050 Ikarashi-2, Niigata 950-2181, Japan., Watanabe T; Department of Materials Science and Technology, Faculty of Engineering, Niigata University, 8050 Ikarashi-2, Niigata 950-2181, Japan., Yoshida K; Department of Materials Science and Technology, Faculty of Engineering, Niigata University, 8050 Ikarashi-2, Niigata 950-2181, Japan., Watabe S; Department of Materials Science and Technology, Faculty of Engineering, Niigata University, 8050 Ikarashi-2, Niigata 950-2181, Japan., Inaba K; Department of Materials Science and Technology, Faculty of Engineering, Niigata University, 8050 Ikarashi-2, Niigata 950-2181, Japan., Hirahara M; Department of Applied Chemistry, Osaka Institute of Technology, 5-16-1 Omiya, Asahi-ku, Osaka 535-8585, Japan., Hatanaka T; Department of Chemistry, Graduate School of Science, Osaka University, 1-1 Machikaneyama, Toyonaka, Osaka 560-0043, Japan., Funahashi Y; Department of Chemistry, Graduate School of Science, Osaka University, 1-1 Machikaneyama, Toyonaka, Osaka 560-0043, Japan., Chandra D; Department of Materials Science and Technology, Faculty of Engineering, Niigata University, 8050 Ikarashi-2, Niigata 950-2181, Japan., Hoshino N; Department of Materials Science and Technology, Faculty of Engineering, Niigata University, 8050 Ikarashi-2, Niigata 950-2181, Japan., Zahran ZN; Department of Materials Science and Technology, Faculty of Engineering, Niigata University, 8050 Ikarashi-2, Niigata 950-2181, Japan., Yagi M; Department of Materials Science and Technology, Faculty of Engineering, Niigata University, 8050 Ikarashi-2, Niigata 950-2181, Japan.

Publikováno v: Inorganic chemistry [Inorg Chem] 2022 Sep 05; Vol. 61 (35), pp. 13956-13967. Date of Electronic Publication: 2022 Aug 24.

Mechanism of H ⁺ dissociation-induced O-O bond formation via intramolecular coupling of vicinal hydroxo ligands on low-valent Ru(III) centers.

Autor: Tanahashi Y; Department of Materials Science and Technology, Faculty of Engineering, Niigata University, Niigata 950-2181, Japan., Takahashi K; Department of Materials Science and Technology, Faculty of Engineering, Niigata University, Niigata 950-2181, Japan., Tsubonouchi Y; Department of Materials Science and Technology, Faculty of Engineering, Niigata University, Niigata 950-2181, Japan., Nozawa S; Photon Factory, High Energy Accelerator Research Organization, Institute of Materials Structure Science, Tsukuba 305-0801, Japan., Adachi SI; Photon Factory, High Energy Accelerator Research Organization, Institute of Materials Structure Science, Tsukuba 305-0801, Japan., Hirahara M; Department of Applied Chemistry, Osaka Institute of Technology, Osaka 535-8585, Japan., Mohamed EA; Department of Materials Science and Technology, Faculty of Engineering, Niigata University, Niigata 950-2181, Japan., Zahran ZN; Department of Materials Science and Technology, Faculty of Engineering, Niigata University, Niigata 950-2181, Japan., Saito K; Department of Materials Science and Technology, Faculty of Engineering, Niigata University, Niigata 950-2181, Japan., Yui T; Department of Materials Science and Technology, Faculty of Engineering, Niigata University, Niigata 950-2181, Japan., Yagi M; Department of Materials Science and Technology, Faculty of Engineering, Niigata University, Niigata 950-2181, Japan; yagi@eng.niigata-u.ac.jp.

Publikováno v: Proceedings of the National Academy of Sciences of the United States of America [Proc Natl Acad Sci U S A] 2021 Dec 28; Vol. 118 (52).

Multi-potential-step chronocoulospectrometry for electrocatalytic water oxidation by a mononuclear ruthenium aquo complex immobilized on a mesoporous ITO electrode.

Autor: Tsubonouchi Y; Department of Materials Science and Technology, Faculty of Engineering, Niigata University, 8050 Ikarashi-2, Niigata 950-2181, Japan. yagi@eng.niigata-u.ac.jp., Honta J; Department of Materials Science and Technology, Faculty of Engineering, Niigata University, 8050 Ikarashi-2, Niigata 950-2181, Japan. yagi@eng.niigata-u.ac.jp., Sato T; Department of Materials Science and Technology, Faculty of Engineering, Niigata University, 8050 Ikarashi-2, Niigata 950-2181, Japan. yagi@eng.niigata-u.ac.jp., Mohamed EA; Department of Materials Science and Technology, Faculty of Engineering, Niigata University, 8050 Ikarashi-2, Niigata 950-2181, Japan. yagi@eng.niigata-u.ac.jp., Zahran ZN; Department of Materials Science and Technology, Faculty of Engineering, Niigata University, 8050 Ikarashi-2, Niigata 950-2181, Japan. yagi@eng.niigata-u.ac.jp., Saito K; Department of Materials Science and Technology, Faculty of Engineering, Niigata University, 8050 Ikarashi-2, Niigata 950-2181, Japan. yagi@eng.niigata-u.ac.jp., Yui T; Department of Materials Science and Technology, Faculty of Engineering, Niigata University, 8050 Ikarashi-2, Niigata 950-2181, Japan. yagi@eng.niigata-u.ac.jp., Yagi M; Department of Materials Science and Technology, Faculty of Engineering, Niigata University, 8050 Ikarashi-2, Niigata 950-2181, Japan. yagi@eng.niigata-u.ac.jp.

Publikováno v: Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2020 Feb 07; Vol. 49 (5), pp. 1416-1423. Date of Electronic Publication: 2020 Jan 08.