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Clean-activation of the B–H bond in closo-decahydrodecaborate [B10H10]2− anion via soft-route

Autor: Daoud Naoufal, Fatima Abi Ghaida, Ahmad Mehdi, Ogaritte Yazbeck, Suzan El Anwar, Manal Diab, Mourtada Srour, Zahra Laila

Publikováno v: Journal of Organometallic Chemistry
Journal of Organometallic Chemistry, Elsevier, 2020, 910, pp.121132. ⟨10.1016/j.jorganchem.2020.121132⟩

Series of closo-decaborate (NH4)2[B10H10] derivatives were prepared by their direct reaction with ligand L (alcohols or nitriles) via an auto-catalyzed reaction with NH4+ present as a counter cation. The reactions were carried out under mild conditio

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::5beca1184952edcfbf98b9eaed6a7ca0
https://hal.archives-ouvertes.fr/hal-02462383

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Synthesis and characterization of click-decahydrodecaborate derivatives by the copper(I) catalyzed [3+2] azide-alkyne cycloaddition reaction

Autor: Gregory B. Dudley, Daoud Naoufal, Ron R. Ramsubhag, Ali Safa, Suzan El Anwar, Zahra Laila, Sami Tlais

Publikováno v: Journal of Organometallic Chemistry. 865:89-94

A facile and rapid access to a wide range of novel 1,2,3-triazoles bearing closo-decahydrodecaborate anion [B10H10]2− has been developed through an efficient general synthetic approach. It is based on the nucleophilic cleavage of 2-tetrahydrofurani

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::67a483da507337e5a73dcbfc8283bec5
https://doi.org/10.1016/j.jorganchem.2018.01.039

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Study of the controlled temperature reaction between closo-decahydrodecaborate and alcohols in H2SO4 medium

Autor: Fatima Abi-Ghaida, Ahmad Mehdi, Suzan Al Anwar, Sami Tlais, Rabih Jahjah, Zahra Laila, Riman Aoun, Daoud Naoufal, Ogaritte Yazbeck

Publikováno v: Main Group Chemistry. 14:301-312

The reactions of the ammonium salt of closo-decahydrodecaborate (NH4)2B10H10 with alcohols were studied in concentrated sulfuric acid medium. Alcohols ROH (R = CH3 ,C 2H5 ,C 3H7, iso-C3H7 ,C 4H9, 2-C4H9, ter-C4H9, C5H11) played the role of solvent an

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::0533f47c3310706b7c10156b8a7970d4
https://doi.org/10.3233/mgc-150173

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Synthesis, characterization and mechanism of formation of 6-substituted nido-B10H13 decaboranes by the opening reaction of closo-decahydrodecaborate [B10H10]2− cage

Autor: Ali Kanj, Hussein Hamad, Ali Safa, Mohieddine El Jamal, Ogaritte Yazbeck, Zahra Laila, Ghassan Ibrahim, Daoud Naoufal, Riman Aoun

Publikováno v: Main Group Chemistry. 12:39-48

The synthesis of new 6-LB10H13 (L = ligand) derivatives of decaborane B10H14 with different ligands was achieved by the opening cage reaction of closo-decahydrodecaborate (NH4)2B10H10 in the presence of a strong acid (HNO3 or H2SO4) in organic solven

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::7232545c3775fd345019fec2d20f58be
https://doi.org/10.3233/mgc-130088

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New triethoxysilylated 10-vertex closo-decaborate clusters. Synthesis and controlled immobilization into mesoporous silica

Autor: Fatima Abi-Ghaida, Daoud Naoufal, Zahra Laila, Ahmad Mehdi, Ghassan Ibrahim

Publikováno v: Dalton Transactions
Dalton Transactions, Royal Society of Chemistry, 2014, ⟨10.1039/c4dt00772g⟩

Novel silylated hydroborate clusters comprising the closo-decaborate cage were prepared and characterized by (1)H, (13)C, (11)B, (29)Si NMR and mass spectroscopy ESI. The synthesis of such silylated clusters was achieved using reactive derivatives of

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::06d2da200ef65bf2333c0ba2a2abf6f3
https://hal.archives-ouvertes.fr/hal-01208305

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