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Synthesis and characterization of tantalum(V) metallaheterocycle (Me2N)3 and chloro-mixed-amide (Me2N)3Ta(Cl)[N(SiMe3)2]

Autor: Hu Cai, Xiao-Zeng You, Xue-Tai Chen, Xianghua Yu, Ziling Xue, Tianniu Chen

Publikováno v: Canadian Journal of Chemistry. 81:1398-1405

A new mixed-amido complex (Me2N)3Ta(Cl)[N(SiMe3)2] (1) was prepared from the reaction of (Me2N)3TaCl2 with 1 equiv. of LiN(SiMe3)2. The reactions of 1 with 1 equiv. of LiN(SiMe3)2 or (Me2N)3TaCl2 with 2 equiv. of LiN(SiMe3)2 gave (Me2N)3[Formula: see

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::1957f8b9c02952daf7a98c3efd454ee8
https://doi.org/10.1139/v03-140

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Early-Transition-Metal Silyl Complexes Free of Anionic π-Ligands. A Comparison of Alkyl and Silyl Ligands

Autor: Ziling Xue

Publikováno v: Comments on Inorganic Chemistry. 18:223-247

A new family of silyl complexes, (RCH2)3MSiR'3 (M = Ti, Zr), (RCH2)2Ta(=CHR)SiR'3 and (RCH2)2W(=CR)SiR'3, which are free of cyclopentadienyl (Cp) or other supporting anionic Ω-ligands, have been prepared and characterized. The silyl ligands are foun

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::547aaa2f3e55add025b4d3482390ae8a
https://doi.org/10.1080/02603599608032723

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Direct Observation of (Me3ECH2)5Ta (E = C, Si) as the Precursors to (Me3ECH2)3Ta:CHEMe3 and (Me3SiCH2)2Ta(.mu.-CSiMe3)2Ta(CH2SiMe3)2. Kinetic and Mechanistic Studies of the Formation of Alkylidene and Alkylidyne Ligands

Autor: Liting Li, Meiling Hung, Ziling Xue

Publikováno v: Journal of the American Chemical Society. 117:12746-12750

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::fbeb942f5b2b8c56db8b3333e4f2ee23
https://doi.org/10.1021/ja00156a011

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ChemInform Abstract: Early-Transition-Metal Silyl Complexes free of Anionic π-Ligands. A Comparison of Alkyl and Silyl Ligands

Autor: Ziling Xue

Publikováno v: ChemInform. 28

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::4f8533b34e99ae4eb9f7d0636e3af62a
https://doi.org/10.1002/chin.199702247

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Ordered arrays of magnetic metal nanotubes and nanowires encapsulated with carbon tubes

Autor: Cuiling Gao, Feifei Tao, Weiwei Lin, Zheng Xu, Ziling Xue

Publikováno v: Journal of nanoscience and nanotechnology. 8(9)

The ordered arrays of magnetic metal (including Fe, Co and Ni) nanotubes and nanowires encapsulated with carbon tubes are controllably synthesized by employing the array of C tubes as second-order template and combining with electrodeposition techniq

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::76b7e1bb2d692022d70d9d29bdba3ad9
https://pubmed.ncbi.nlm.nih.gov/19049046

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Synthesis and spectroscopic characterization of diruthenium .sigma.,.pi.-vinyl complexes Ru2[.mu.-O:C(NMe2),.mu.-.sigma.,.pi.-C(Ar):C(Ar)H](CO)5PPh3, (Ar = phenyl, p-tolyl) and Ru2[.mu.-O:C(NMe2), .mu.-.sigma.,.pi.-C(Ph):CH2](CO)5PPh3. Crystal and molecular structures of Ru2[.mu.-O:C(NMe2), .mu.-.sigma.,.pi.-C(C6H4Me-p):C(C6H4Me-p)H](CO)5PPh3 and Ru2[.mu.-O:C(NMe2),.mu.-.sigma.,.pi.-C(Ph):CH2](CO)5PPh3

Autor: Ziling Xue, Werner J. Sieber, Carolyn B. Knobler, Herbert D. Kaesz

Publikováno v: Journal of the American Chemical Society. 112:1825-1833

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::7b77fac6c6095912e69b923419566a55
https://doi.org/10.1021/ja00161a028

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Direct observation of eta 2-imine formation through beta-H abstraction between amide ligands. Neutron and X-ray diffraction structure of a dihydride imine ditantalum complex

Autor: Hu, Cai, Tianniu, Chen, Xiaoping, Wang, Arthur J, Schultz, Thomas F, Koetzle, Ziling, Xue

Publikováno v: Chemical communications (Cambridge, England). (3)

Reactions of Ta(NMe2)5 with D2SiR'Ph (R' = Me, Ph) were found to give a dideuteride eta 2-imine complex (Me2N)3Ta(mu-D)2(mu-N-eta 2-N,C-CH2NMe)Ta(NMe2)3(1-d2) through C-H activation of an amide ligand via beta-H abstraction, and the structure of 1 wa

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=pmid________::5a83c5c702ab6a58d18c891e25cd3e51
https://pubmed.ncbi.nlm.nih.gov/12120379

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Imprint Coating: A Novel Synthesis of Selective Functionalized Ordered Mesoporous Sorbents

Autor: Sheng, Dai, Mark C, Burleigh, Yongsoon, Shin, Charles C, Morrow, Craig E, Barnes, Ziling, Xue

Publikováno v: Angewandte Chemie (International ed. in English). 38(9)

Molecular imprinting of surfaces of mesoporous sorbents is a novel method for introducing template-selective recognition sites. This method makes use of the unique surface environment of hexagonally packed mesopore surfaces of selected pore sizes (se

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=pmid________::2220739ecc0138b8668969847888743b
https://pubmed.ncbi.nlm.nih.gov/29711718

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Conference

CHEMISTRY IN MOLECULAR APPROACHES TO MICROELECTRONIC DIFFUSION BARRIER MATERIALS.

Autor: XIAOZHAN LIU, HU CAI, ZHONGZHI WU, YIHUI YANG, TIANNIU CHEN, ZILING XUE, VALLET, CATHERINE E., BEACH, DAVID B., ZUHR, RAY A.

Publikováno v: Frontiers of Solid State Chemistry, Proceedings of the International Symposium on Solid State Chemistry in China; 2002, p427-434, 8p

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