Zobrazeno 1 - 10
of 15
pro vyhledávání: '"Z. M. Sabirov"'
Publikováno v:
Kinetics and Catalysis. 42:310-316
Several types of active sites can be formed during the polymerization of dienes in the presence of lanthanide catalytic systems. These sites differ in the nearest environment of a lanthanide atom (the numbers of chlorine and carbon atoms) and in the
Publikováno v:
Russian Chemical Bulletin. 47:1280-1283
The kinetics and mechanism of thermal decomposition of adamantyl-containing organosilicon peroxides in a solution inn-nonane were studied. The relationship between the structure of the peroxide and the rate and mechanism of thermolysis was establishe
Publikováno v:
Journal of Applied Polymer Science. 89:601-603
On the basis of quantum-chemical calculations, it was shown that among six types of active centers (ACs) that can form during the polymerization of butadiene with lanthanide-based catalytic systems, five types (containing electron-accepting chlorine
Publikováno v:
Theoretical and Experimental Chemistry. 27:643-646
On the basis of quantum-chemical calculations of models of active centers, a suggested mechanism of kinetic stereocontrol of the microsctructure in polymerization of butadiene under the influence of the catalytic system NdCl3 · 3TBP-HA1 (i-C4H9)2 ha
Publikováno v:
Polymer Science U.S.S.R.. 33:387-417
The results of investigations in the field of polymerization of conjugated dienes on cis-regulating lanthanide-containing catalysts of the ion-coordination type are reviewed. The influence of the composition of the catalysts, the structure of the mon
Publikováno v:
Polymer Science U.S.S.R.. 33:2161-2167
The polymerization of piperilene has been studied on exposure to the catalytic system VOCl 3 TiCl 4 Al( iso -C 4 H 9 ) 3 prepared with a fractionated supply of the organoaluminium component. It is known that the stereospecificity of the action
Autor:
A. I. Pavlyuchko, Z. M. Sabirov, I. O. Kulago, Boris S. Orlinson, Yu. B. Monakov, O. A. Kuznechikov, V. N. Urazbaev, Ivan A. Novakov
Publikováno v:
Russian Chemical Bulletin. 48:282-284
The reactivity of adamantane-containing diamines in the reactions with dianhydrides of 3,4,3′, 4′-tetracarboxydiphenyl oxide was studied as a function of the parameters of their electronic structures. It was found that the reactivity changes in p
Autor:
Yu. B. Monakov, Z. M. Sabirov
Publikováno v:
Inorganica Chimica Acta. 169:221-224
Quantochemical studies have been carried out for the models of active centres of butadiene polymerization on the Nd-Al catalytic system. The syn -isomeric forms of active centres have been found energetically preferable over the anti -isomeric forms;
Publikováno v:
Journal of Polymer Science Part A: Polymer Chemistry. 31:2419-2421
The polymerization of butadiene with the catalytic system NdCl3 · 3TBP-(1C4H9)2AlH (TBP-tributyl phosphate) was studied. With regard to the anti-syn-isomerization of both free- and monomer-complexed active centers, the kinetic scheme of the propagat
Publikováno v:
Mendeleev Communications. 11:157-158
The unusual dependence of butadiene conversion and polymer microstructure on the ratio Mg/Nd or Al/Nd during the polymeriza-tion of butadiene under the action of NdCl3·3TBPAlBu3iMgBu(i-C8H17) can be explained by the formation of a set of active cent