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Identification, monitoring, and reaction kinetics of reactive trace species using time-resolved mid-infrared quantum cascade laser absorption spectroscopy: development, characterisation, and initial results for the CH2OO Criegee intermediate

Autor: Z. S. Mir, M. Jamieson, N. R. Greenall, P. W. Seakins, M. A. Blitz, D. Stone

Publikováno v: Atmospheric Measurement Techniques, Vol 15, Pp 2875-2887 (2022)

The chemistry and reaction kinetics of reactive species dominate changes to the composition of complex chemical systems, including Earth's atmosphere. Laboratory experiments to identify reactive species and their reaction products, and to monitor the

Externí odkaz: https://doaj.org/article/21c28a00a8aa4a2f828e60450cc81737

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Kinetic studies of C

Autor: N U M, Howes, Z S, Mir, M A, Blitz, S, Hardman, T R, Lewis, D, Stone, P W, Seakins

Publikováno v: Physical chemistry chemical physics : PCCP. 20(34)

Recent, direct studies have shown that several reactions of stabilized Criegee intermediates (SCI) are significantly faster than indicated by earlier indirect measurements. The reaction of SCI with SO2 may contribute to atmospheric sulfate production

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=pmid________::d62874a718715121788aa75e4da07c51
https://pubmed.ncbi.nlm.nih.gov/30118123

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