Zobrazeno 1 - 3
of 3
pro vyhledávání: '"Yutaro Udagawa"'
Publikováno v:
Organicbiomolecular chemistry. 20(42)
We disclose the first synthesis of the marine natural product, (+)-boneratamide A, whose structure is composed of a terpene unit linkedivia/ian amide bond to a pyroglutamic acid moiety. The key step in this route is a bioinspired Ugi reaction of (+)-
Autor:
Seijiro Hosokawa, Yutaro Udagawa, Toshiki Yamasaki, Yoshiyasu Ichikawa, Toshiya Masuda, Keisuke Nakanishi
Publikováno v:
Synthesis. 51:2305-2310
A pathway is proposed for the biosynthesis of the unique homodimeric terpene, halichonadin H. The proposed biosynthetic pathway involves two key Passerini reactions of eudesmane-type terpene isocyanides. The Passerini reaction of a model terpene isoc
Autor:
Yoshiyasu Ichikawa, Keiji Nakano, Mitsutoshi Maeda, Seiya Sato, Keisuke Nakanishi, Seijiro Hosokawa, Toshiya Masuda, Yutaro Udagawa
Publikováno v:
Organicbiomolecular chemistry. 18(4)
The first total synthesis of a marine natural product, exigurin, has been accomplished in 13 steps starting from (+)-menthone. The key intermediate (−)-10-epi-axisonitrile-3 was prepared by stereoselective intramolecular cyclopropanation followed b