Zobrazeno 1 - 10
of 19
pro vyhledávání: '"Yurii V, Svyaschenko"'
Publikováno v:
Chemistry - A European Journal. 22:4247-4255
Versatile synthetic protocols for 2,7- and 3,6-diacetylenic fluorene-9-ylidene phosphanes (F9Ps) were developed. Protodesilylation of trimethylsilyl-protected acetylenic F9Ps affords terminal acetylenes that can be employed in Sonogashira and Glaser-
Autor:
Daoud Naoufal, Fatima Allouch, Hélène Cattey, Nejib Dwadnia, Marie-José Penouilh, Nikolay V. Vologdin, Nadine Pirio, Julien Roger, Jean-Cyrille Hierso, Ridha Ben Salem, Yurii V. Svyaschenko
Publikováno v:
Organometallics. 34:5015-5028
Hexasubstituted hybrid tetradentate (N,N′,P,P′)-ferrocenes bearing phosphino and aminomethyl groups, plus hindering tert-butyl moieties, were synthesized by using two different strategies: a “diverging” synthesis involving successive function
Publikováno v:
Phosphorus, Sulfur, and Silicon and the Related Elements. 190:638-646
lambda(3)-phosphahexatrienes were prepared from ethoxyvinyl phosphinophosphonates using the phospha-Wittig-Horner reaction. The title compounds can be easily prepared in three steps starting from dichlorophosphines with good overall yields. Although
Publikováno v:
Angewandte Chemie. 125:6612-6615
Autor:
Dmitriy A. Sibgatulin, Aleksandr N. Kostyuk, Dmitriy M. Volochnyuk, Eduard B. Rusanov, Yurii V. Svyaschenko, Bogdan Barnych
Publikováno v:
Heteroatom Chemistry. 20:194-201
The reaction of β-dialkylaminocrotontriles with phosphorus(III) halides has been investigated. The basicity of the dialkylamino group influences the phosphorylation markedly, with pyrrolidine being the amine of choice. It was found that a solvent an
Publikováno v:
Tetrahedron. 63:5656-5664
The alkylation of 2-(diphenylphosphino)-3-pyrrolidin-1-ylbut-2-enenitrile with a set of bromoacetophenones has been studied. Cyclization of the phosphonium salts into 6-cyano-3-hydroxy-3-aryl-1,1-diphenyl-5-pyrrolidin-1-yl-1,2,3,4-tetrahydrophosphini
Publikováno v:
Tetrahedron. 61:9263-9272
A novel approach to λ 5 -phosphinines has been discovered. Phosphonium salts bearing an alkyl group and the residue of β-dialkylaminocrotonic acid react with DMADMF affording λ 5 -phosphinines. A plausible mechanism of the reaction is offered.
Autor:
Dmitriy M. Volochnyuk, Yurii V. Svyaschenko, Nikolai v. Lysenko, Andrei A. Tolmachev, Alexandr M. Pinchuk, A. N. Kostyuk
Publikováno v:
Tetrahedron Letters. 44:6487-6491
The reaction of ‘push–pull’ enamines—derivatives of β-aminocrotonic acid with diphenylchlorophosphine has been investigated. Structural sensitivity of the reaction was found and is discussed.
Publikováno v:
Tetrahedron Letters. 51:6316-6318
A novel approach to 1,2λ5-azaphosphinines has been elaborated. Aminophosphonium chlorides bearing a β-dialkylaminocrotonic nitrile residue react with N,N-dimethylformamide dimethylacetal to afford 1,2λ5-azaphosphinines.
Autor:
Nadiya V. Shevchuk, Aleksandr N. Kostyuk, Yurii V. Svyaschenko, Dmitriy M. Volochnyuk, Bogdan Barnych
Publikováno v:
The Journal of organic chemistry. 76(15)
We experimentally verified an assumption that the substitution of a carbon atom with a pentavalent phosphorus atom in 1-alkoxy (dialkylamino) hexatrienes will not hamper its ability to electrocyclize. A series of 1-, 3-, and 5-phosphahexatrienes were