Aluminum Salen Complexes Modified with Unsaturated Alcohol: Synthesis, Characterization, and Their Activity towards Ring-Opening Polymerization of ε-Caprolactone and D,L-Lactide

Autor: Kirill V. Zaitsev, Andrey D. Trubachev, Yuri F. Oprunenko, Yuliya A. Piskun, Irina V. Vasilenko, Andrei V. Churakov, Sergei V. Kostjuk

Publikováno v: Molecules, Vol 28, Iss 3, p 1262 (2023)

A highly efficient one-step approach to the macromonomer synthesis using modified aluminum complexes as catalysts of ring-opening polymerization (ROP) of ε-caprolactone and D,L-lactide was developed. The syntheses, structures, and catalytic activiti

Externí odkaz: https://doaj.org/article/af530926bfb84824906874432d0ddcf3

Toward the Synthesis of Heteroleptic Zinc ROP Initiators Based on Pyridine-Containing Monoalcohols by Tuning Ligand Substituents

Autor: Ekaterina A. Kuchuk, Badma N. Mankaev, Kirill V. Zaitsev, Maxim V. Zabalov, Ekaterina A. Zakharova, Yuri F. Oprunenko, Andrei V. Churakov, Elmira Kh. Lermontova, Galina S. Zaitseva, Sergey S. Karlov

Publikováno v: Organometallics.

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::c4f544fd7eb98eb63a67c1d423bfbf1b
https://doi.org/10.1021/acs.organomet.2c00611

DFT Investigation of the η6 ⇌ η6-Inter-ring Haptotropic Rearrangement of the Group 8 Metals Complexes [(graphene)MCp]+ (M = Fe, Ru, Os)

Autor: Yuri F. Oprunenko, Franck Gam, Igor P. Gloriozov, Nikolay S. Zhulyaev, Piotr I. Dem'yanov, Jean-Yves Saillard, Aleksey E. Kuznetsov, Mikhail S. Nechaev

Publikováno v: Journal of Physical Chemistry A
Journal of Physical Chemistry A, American Chemical Society, 2021, 125 (1), pp.366-375. ⟨10.1021/acs.jpca.0c08251⟩
Journal of Physical Chemistry A, 2021, 125 (1), pp.366-375. ⟨10.1021/acs.jpca.0c08251⟩

International audience; Metalcyclopentadienyl complexes (MCp) (M = Fe, Ru, Os) bound to the large polyaromatic hydrogenated hydrocarbon (PAH) CH used as a model for pristine graphene have been studied using a density functional theory (DFT) generaliz

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d1b1a648471cfabef6cbd3961f254546
https://doi.org/10.1021/acs.jpca.0c08251

DFT study of inter-ring haptotropic rearrangement in CpRu+ complexes of polycyclic aromatic ligands

Autor: Franck Gam, Kirill V. Zaitsev, Mikhail S. Nechaev, Jean-Yves Saillard, Yuri F. Oprunenko, Igor P. Gloriozov

Publikováno v: Journal of Organometallic Chemistry
Journal of Organometallic Chemistry, 2019, 889, pp.9-14. ⟨10.1016/j.jorganchem.2019.03.016⟩
Journal of Organometallic Chemistry, Elsevier, 2019, 889, pp.9-14. ⟨10.1016/j.jorganchem.2019.03.016⟩

International audience; Inter-ring haptotropic rearrangements (IRHRs) of different types are well-known phenomena in organometallic and catalytic chemistry. So far, they are reported for transition metal complexes with carbo-and heterocyclic polyarom

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::085e022f21323a96ae627bcbb141709d
https://doi.org/10.1016/j.jorganchem.2019.03.016

Donor-acceptor molecular oligogermanes: Novel properties and structural aspects

Autor: Andrei V. Churakov, Sergey S. Karlov, Kevin Lam, Yuri F. Oprunenko, Kirill V. Zaitsev, Galina S. Zaitseva, Zhaisan Zhanabil, Guldana Issabayeva, Anastasia V. Kharcheva

Publikováno v: Journal of Organometallic Chemistry. 867:228-237

The linear oligogermyl amide 2, Ph3GeGeMe2NMe2, was obtained by reacting Ph3GeLi with 1, Me2Ge(Cl)NMe2. The amide 2 was used for the synthesis of molecular oligogermanes 3, Ph3GeGeMe2Ge(C6F5)3, and 4, [Ph3GeGeMe2]2Ge(C6F5)2, containing electron donor

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::60b0bf23d82c1805e15c97478c54e0aa
https://doi.org/10.1016/j.jorganchem.2017.11.029