Zobrazeno 1 - 10
of 20
pro vyhledávání: '"Yun-Zhu Liu"'
Publikováno v:
Dalton Transactions. 52:6668-6676
The key to optimizing energy-consuming catalytic conversions lies in acquiring a fundamental understanding of the nature of the active sites and the mechanisms at an atomically precise level, while it is challenging due to the complexity of real-life
Publikováno v:
The Journal of Physical Chemistry A. 126:5294-5301
Publikováno v:
ACS Catalysis. 12:8768-8775
Publikováno v:
Physical Chemistry Chemical Physics. 24:29765-29771
Identifying the structural configurations of precursors for CO dissociation is fundamentally interesting and industrially important in the fields of, e.g., Fischer–Tropsch synthesis.
Publikováno v:
Dalton Transactions. 51:11491-11498
A RhTaC2− cluster can reduce four CO2 molecules consecutively. The pivotal roles of Rh–Ta synergy and the C2 ligand in driving CO2 reduction were rationalized. A fundamental strategy to alleviate carbon deposition in the CO2 atmosphere was provid
Publikováno v:
Physical Chemistry Chemical Physics. 24:14616-14622
We experimentally identify the gas-phase species Rh2− that can drive the reverse water–gas shift (RWGS, CO2 + H2 → CO + H2O) reaction. The generation of a gas-phase H2O molecule and [Rh2(CO)ads]− at room temperature was identified and the onl
Publikováno v:
The Journal of Physical Chemistry Letters. 12:6519-6525
The generation and characterization of multiple metal-metal (M-M) bonds between early and late transition metals is vital to correlate the nature of multiple M-M bonds with the related reactivity in catalysis, while the examples with multiple M-M bon
Publikováno v:
Dalton transactions (Cambridge, England : 2003). 51(30)
Noble metals dispersed on transition-metal carbides exhibit extraordinary activity in CO
Publikováno v:
The Journal of Physical Chemistry A. 125:3710-3717
Laser ablation generated CoCDn- (n = 0-4) anions were mass selected and then reacted with CO2 in an ion trap reactor. The reactions were characterized by mass spectrometry and quantum chemical calculations. The experimental results demonstrated that
Publikováno v:
The Journal of Physical Chemistry A. 124:8414-8420
The hydrogenation of CO2 into value-added complexes is of great importance for both environmental and economic issues. Metal hydrides are good models for the active sites to explore the nature of CO2 hydrogenation; however, the fundamental insights i