Zobrazeno 1 - 5
of 5
pro vyhledávání: '"Yuko Sakamaki"'
Publikováno v:
Tetrahedron Letters. 41:4603-4607
The highly enantioselective synthesis of 1,1,1-trifluoroalkan-2-ols has been achieved by hydrogenating 1,1,1-trifluoroalkan-2-one enol acetates in the presence of chiral ruthenium catalysts. An enol acetate, 2-acetoxy-3,3,3-trifluoro-1-(phenylthio)pr
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::308f3968de95f031a0b62a78ddc9dc64
https://doi.org/10.1016/s0040-4039(00)00643-2
https://doi.org/10.1016/s0040-4039(00)00643-2
Autor:
Kentaro Yamaguchi, Yuko Sakamaki, Norihiko Tani, Tomohiko Ohwada, Yoji Kabasawa, Masatoshi Kawahata, Yuko Otani
Neighboring group participation is one of the fundamental interactions in organic reactions and can influence the reaction rate, stereoselectivity, and reaction pathway through transient carbon-carbon or carbon-heteroatom bond formation. The latter c
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::69d73c4d35b7c82c875ea050e2592114
https://europepmc.org/articles/PMC3600509/
https://europepmc.org/articles/PMC3600509/
Publikováno v:
ChemInform. 31
The highly enantioselective synthesis of 1,1,1-trifluoroalkan-2-ols has been achieved by hydrogenating 1,1,1-trifluoroalkan-2-one enol acetates in the presence of chiral ruthenium catalysts. An enol acetate, 2-acetoxy-3,3,3-trifluoro-1-(phenylthio)pr
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::5fe09a3da0cb8e15cfa8ec789304c37e
https://doi.org/10.1002/chin.200036028
https://doi.org/10.1002/chin.200036028
Publikováno v:
Organic letters. 3(3)
[figure: see text] The asymmetric hydrogenation of trifluoromethyl ketones to yield chiral alpha-trifluoromethyl alcohols with enantiomeric excesses up to 98% was achieved in the presence of chiral rhodium-(amidephosphine-phosphinite) complexes.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::8d819cc20da4799eae3fa111183c06c1
https://pubmed.ncbi.nlm.nih.gov/11428038
https://pubmed.ncbi.nlm.nih.gov/11428038
Publikováno v:
ChemInform. 32
The asymmetric hydrogenation of trifluoromethyl ketones to yield chiral α-trifluoromethyl alcohols with enantiomeric excesses up to 98% was achieved in the presence of chiral rhodium-(amidephosphine-phosphinite) complexes.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::255978d03db0343768a6f963aadf2914
https://doi.org/10.1002/chin.200120034
https://doi.org/10.1002/chin.200120034