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pro vyhledávání: '"Yuki Kakeno"'
Autor:
Yuki Matsuki, Nagisa Ohnishi, Yuki Kakeno, Shunsuke Takemoto, Takuya Ishii, Kazunori Nagao, Hirohisa Ohmiya
Publikováno v:
Nature Communications, Vol 12, Iss 1, Pp 1-8 (2021)
Use of aryl halides as coupling precursors typically occurs through transition metal catalysis and/or photoredox chemistry, which requires some combination of light, metals, and oxidants or reductants. Here, the authors show a method to generate aryl
Externí odkaz:
https://doaj.org/article/f36b6c5bc0004213ae418b24ec57fb2a
Publikováno v:
Journal of the American Chemical Society. 141(9)
We found that N-heterocyclic carbene catalysis promoted the unprecedented decarboxylative coupling of aryl aldehydes and tertiary or secondary alkyl carboxylic acid-derived redox-active esters to produce aryl alkyl ketones. The mild and transition-me