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Akademický článek

Preparations of trans- and cis-μ-1,2-Peroxodiiron(III) Complexes

Autor: Yuji Kajita, Masaki Kubo, Hidekazu Arii, Shinya Ishikawa, Yamato Saito, Yuko Wasada-Tsutsui, Yasuhiro Funahashi, Tomohiro Ozawa, Hideki Masuda

Publikováno v: Molecules, Vol 29, Iss 1, p 205 (2023)

The iron(II) complex with cis,cis-1,3,5-tris(benzylamino)cyclohexane (Bn3CY) (1) has been synthesized and characterized, which reacted with dioxygen to form the peroxo complex 2 in acetone at −60 °C. On the basis of spectroscopic measurements for

Externí odkaz: https://doaj.org/article/99964e4dfc8341ee8f66f1dba24783dc

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Akademický článek

The Steric Effect in Preparations of Vanadium(II)/(III) Dinitrogen Complexes of Triamidoamine Ligands Bearing Bulky Substituents

Autor: Yoshiaki Kokubo, Itsuki Igarashi, Kenichi Nakao, Wataru Hachiya, Shinichi Kugimiya, Tomohiro Ozawa, Hideki Masuda, Yuji Kajita

Publikováno v: Molecules, Vol 27, Iss 18, p 5864 (2022)

The reactions of newly designed lithiated triamidoamines Li3LR (R = iPr, Pen, and Cy2) with VCl3(THF)3 under N2 yielded dinitrogen–divanadium complexes with a μ-N2 between vanadium atoms [{V(LR)}2(μ-N2)] (R = iPr (1) and Pen (2)) for the former t

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Akademický článek

Tetrachlorido[(diphenylphosphino)diphenylphosphine oxide-κO]zirconium(IV) benzene monosolvate. Corrigendum

Autor: Takahiko Ogawa, Yuji Kajita, Hideki Masuda

Publikováno v: Acta Crystallographica Section E, Vol 66, Iss 2, Pp e16-e16 (2010)

The chemical name of the title compound in the paper by Ogawa, Kajita & Masuda [Acta Cryst. (2009), E65, m1129] is corrected.

Externí odkaz: https://doaj.org/article/cb465e2968774437929a2ff19fe35920

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Akademický článek

{μ-Bis(1-methylimidazol-2-yl)methane-κ2N3:N3′}bis{[(1-methylimidazol-2-yl)methane-κ2N3,N3′]copper(I)} bis(trifluoromethanesulfonate)

Autor: Jun Matsumoto, Yuji Kajita, Hideki Masuda

Publikováno v: Acta Crystallographica Section E, Vol 65, Iss 11, Pp m1286-m1287 (2009)

The title compound, [Cu2(C9H12N4)3](CF3SO3)2, contains two CuI ions, three bis(1-methylimidazol-2-yl)methane (Me2BIM) ligands, and two trifluoromethanesulfonate anions in the asymmetric unit. Each CuI ion has a distorted trigonal-planar geometry and

Externí odkaz: https://doaj.org/article/84140139946c4b0e936435b705336d75

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Akademický článek

Tetrachlorido[(diphenylphosphino)diphenylphosphine oxide-κO]zirconium(IV) benzene monosolvate

Autor: Takahiko Ogawa, Yuji Kajita, Hideki Masuda

Publikováno v: Acta Crystallographica Section E, Vol 65, Iss 9, Pp m1129-m1129 (2009)

In the title centrosymmetric mononuclear ZrIV compound, [ZrCl4{P(O)(C6H5)2P(C6H5)2}2]·C6H6, the central ZrIV ion is coordinated by two O atoms from two symmetry-related (diphenylphosphino)diphenylphosphine ligands and four Cl atoms in a distorted oc

Externí odkaz: https://doaj.org/article/2d78919a797e4ddda24baab9bab4b955

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