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pro vyhledávání: '"Yu. Ya. Skolis"'
Publikováno v:
Russian Journal of Physical Chemistry A. 88:372-376
The thermodynamic properties and oxygen stoichiometry of Ba2Cu3O5 + δ are studied by means of the electromotive force (EMF) with a fluoride electrolyte, dissolution calorimetry, and thermogravimetry. It is shown that the temperature dependence of th
Autor:
M. L. Kovba, Yu. Ya. Skolis
Publikováno v:
Russian Journal of Physical Chemistry A. 85:2057-2061
Temperature dependences of the Gibbs energy of the formation of strontium manganite (SrMn3O6 − δ, SrMnO3, Sr2MnO4) and fluorine manganite (Sr2.5Mn6O12.5 − δF2) from simple oxides, oxygen, and SrF2, respectively, are determined by EMF with fluor
Publikováno v:
Russian journal of physical chemistry A
The existence of the [SrF(0.8)O(0.1)](2.5)[Mn(6)O(12)] = Sr(2.5)Mn(6)O(12.5 - delta)F(2) compound was established in the SrO-Mn(2)O(3)-SrF(2) system at 900A degrees C and p(O(2)) = 1 atm. The crystal structure of strontium fluoromanganite was determi
Publikováno v:
Russian Journal of Physical Chemistry. 80:47-50
The temperature dependences of the Gibbs energies of formation of RMnO3 (R = Y, Dy) from the coexisting phases R2O3 + 2RMn2O5 = 4RMnO3 + 0.5O2 were determined by the electromotive force (EMF) method with a fluorine ion conducting electrolyte. The tem
Publikováno v:
Thermochimica Acta. :567-573
The existence of an homogenity range of BaCu1 + yO2 + x in respect of copper was established by EMF measurement and DTA, and the nonstoichiometry index (xt) of oxygen versus temperature (t) was measured by TG in static dry oxygen. The values obtained
Autor:
Yu. Ya. Skolis, A.F. Maiorova, S. N. Mudretsova, G.N. Maso, L.A. Khramtsova, M.V. Gorbatcheva, M. L. Kovba
Publikováno v:
Thermochimica Acta. :101-107
The superconducting compound HgBa2CuO4 + x and its precursor Ba2CuO3 + y have been studied in an oxygen atmosphere by TG-DTA in the temperature interval 20–1100°C. It was supposed that the succession of chemical processes taking place during the h