NH-Polyfluoroalkyl іminophosphonates in the synthesis of α-amino-α-polyfluoroalkyl-γ-oxobutylphosphonic acids

Autor: O. V. Stanko, Y. P. Yelenich, P. P. Onys’ko, Yu. V. Rassukana

Publikováno v: Журнал органічної та фармацевтичної хімії, Vol 17, Iss 2, Pp 5-10 (2019)

Aim. To develop the preparative method for the synthesis of optically active α-amino-α-polyfluoroalkyl-γ-oxobutylphosphonic acids as new promising chiral building blocks. Results and discussion. It has been shown that the reaction of NH-polyfluor

Externí odkaz: https://doaj.org/article/c1b7be6d153e4e97a3165085f22a587c

Imidoylphosphonates-Alkylideneaminophosphonates Interconversions via Biomimetic Transamination Reaction

Autor: P. P. Onys'ko, T. V. Kim, Yu. V. Rassukana, Olena I. Kyselyova, Anatoly D. Synytsya

Publikováno v: Phosphorus, Sulfur, and Silicon and the Related Elements. 186:721-728

The data on prototropy in imidoylphosphonates containing α-hydrogen atoms in the N-alkyl group of the C˭N bond were systematized and generalized. Imidoylphosphonates-alkylideneaminophosphonates interconversions via biomimetic transamination reactio

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::f5dcb5750433cde51fcbe28ff1e47284
https://doi.org/10.1080/10426507.2010.520287

Imidoyl Chlorides: New Promising Building Blocks in Synthesis of α-Aminophosphoryl Compounds

Autor: Yu. V. Rassukana, P. P. Onys'ko, O. A. Sinitsa

Publikováno v: Phosphorus, Sulfur, and Silicon and the Related Elements. 183:399-405

Synthetic and mechanistic aspects relevant to nucleo philic phosphorylation of imidoyl chlorides, their potentialities in preparing functionalized α-aminophosphoryl compounds were discussed.

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::7463c6c04c7716f59888e1495835166f
https://doi.org/10.1080/10426500701735338

Novel Rearrangement of Spirophosphoranes

Autor: P. P. Onys'ko, Y. G. Vlasenko, Anatoly D. Synytsya, Andrii V. Bezdudny, Yu. V. Rassukana, Alexander N. Chernega, S. V. Lobanov

Publikováno v: Phosphorus, Sulfur, and Silicon and the Related Elements. 188:173-175

Reactions of N-trifluoroacetyl trifluoroacetimidoyl chloride with acyclic or cyclic phosphites proceed by the cheletropic 1,4-cycloaddition scheme to form mono- or spirocyclic phosphoranes. The spirophosphorane resulting from the reaction with diethy

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::0331abcb05d677564ccdb364cb5ee952
https://doi.org/10.1080/10426507.2012.743546

Synthesis, the antioxidant and antibacterial activity of fluoroalkyl substituted thiazolidinones and thiazinanones incorporating an aminophosphonate or aminocarboxylate fragment

Autor: M. M. Kornet, Ya. Ya. Khomutnyk, P. P. Onys'ko, Yu. V. Rassukana, O. A. Brazhko, Anatoly D. Synytsya, Ivanna P. Yelenich

Publikováno v: Журнал органічної та фармацевтичної хімії; Том 12, № 3(47) (2014): Журнал органічної та фармацевтичної хімії; 45-48
Žurnal organìčnoï ta farmacevtičnoï hìmìï; Том 12, № 3(47) (2014): Žurnal organìčnoï ta farmacevtičnoï hìmìï; 45-48
Журнал органической и фармацевтической химии; Том 12, № 3(47) (2014): Журнал органической и фармацевтической химииС; 45-48

Циклоконденсацією флуороалкілзаміщених імінофосфонатів та імінокарбоксилатів, RFCH(R)=NH [R = (EtO)2P(O), COOMe, RF = CF3, CHF2], з тіогліколевою, 3-меркапт�

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::bf41038d329220da0f9d320d67d05474
http://ophcj.nuph.edu.ua/article/view/ophcj.14.814