Zobrazeno 1 - 10
of 20
pro vyhledávání: '"Yu. V. Belokopytov"'
Publikováno v:
Theoretical and Experimental Chemistry. 43:405-410
An increase in the propylene output in the oxidative dehydration of propane on V2O5/TiO2-SiO2 was observed after prior reduction of V2O5 in the reaction mixture to V2O4, which reduces the destructive chemisorption of propylene. A low titanium dioxide
Publikováno v:
Theoretical and Experimental Chemistry. 39:364-368
We have used potentiometric titration with tetrabutylammonium hydroxide to determine the acid center content on the outer surface of dealuminated natural and synthetic mordenites. We have established a symbatic relationship between the 2,2-dimethylbu
Autor:
Yu. A. Serguchev, Yu. V. Belokopytov
Publikováno v:
Kinetics and Catalysis. 42:174-181
The catalytic hydrogenolysis of hexachlorobenzene and hexachlorocyclohexanes (isomer mixture) on a nickel–chromia catalyst and hexachlorobenzene hydrogenolysis intermediates (1,2,4,5-tetrachlorobenzene, 1,2,4-trichlorobenzene, 1,2-dichlorobenzene,
Autor:
Yu. V. Belokopytov
Publikováno v:
Theoretical and Experimental Chemistry. 34:119-133
The results of investigations into the processes involved in the heterogeneous catalytic oxidation of benzene and its derivatives at the L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, are summarized. The
Autor:
Yu. V. Belokopytov
Publikováno v:
ChemInform. 30
The results of investigations into the processes involved in the heterogeneous catalytic oxidation of benzene and its derivatives at the L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, are summarized. The
Publikováno v:
Theoretical and Experimental Chemistry. 26:444-449
In the present work an IR spectroscopic and thermodesorption investigation of the surface compounds formed by chlorobenzene on a vanadium oxide catalyst was undertaken. It was established that in the initial period of adsorption chlorobenzene forms a
Autor:
Yu. V. Belokopytov
Publikováno v:
Theoretical and Experimental Chemistry. 34:280-282
The reaction mechanism in the hydrogenolysis of chlorobenzene over nickel-chromium catalyst has been investigated. It is concluded that the process takes place on the catalyst surface, through dissociatively adsorbed chlorobenzene and hydrogen.
Autor:
I. V. Davidenko, Yu. V. Belokopytov
Publikováno v:
Theoretical and Experimental Chemistry. 28:354-356
The complete catalytic oxidation of benzene and its chlorine derivatives is shown to proceed via the formation of a π-complex that is further transformed into phenolate, carboxylate, and carbonate surface compounds, which give rise through desorptio
Publikováno v:
Reaction Kinetics and Catalysis Letters. 27:7-10
TPD studies of the interaction of propene with oxidized chromium molybdate have revealed that propene is reversibly chemisorbed on the Cr(MoO4)3 surface. The kinetic order of propene desorption is close to 2, which indicates a dissociative character
Publikováno v:
Theoretical and Experimental Chemistry. 21:242-245
Programmed thermal desorption was used to investigate the interaction of benzene with vanadium-molybdenum oxide catalysts. It was established that the amount of maleic anhydride desorbed from the catalyst surface depends on the catalyst composition a