Zobrazeno 1 - 10
of 27
pro vyhledávání: '"Yu. K. Kushmuradov"'
Publikováno v:
Chemistry of Natural Compounds. 15:308-314
The three-dimensional structure of the alkaloid sophoridine C15H24ON2 has been studied by x-ray structural analysis; the parameters of the elementary cell are: a=5.458, b=10.640, c=11.989 A; γ=99.7°; z=2; space group P22. The experimental set was o
Autor:
Samat Talipov, T. F. Aripov, Yu. K. Kushmuradov, S. Kuchkarov, Bakhtiyar T. Ibragimov, G. N. Tishchenko
Publikováno v:
Chemistry of Natural Compounds. 17:546-551
The structure of tetrahydroneosophoramine has been studied by x-ray structural analysis. Rings A, B, and C have the chair conformation, and ring D the half-chair conformation. On the basis of a semiquantitative analysis it has been shown that the str
Publikováno v:
Chemistry of Natural Compounds. 13:451-454
On the basis of spectral characteristics and chemical transformations, a new alkaloid with the composition C15H22O2N2 isolated fromSophora alopecuroides has been assigned the most probable structure of 13,14-dehydrosophoridine N-oxide.
Publikováno v:
Chemistry of Natural Compounds. 17:552-557
The molecular and crystal structure of lehmannine in its monohydrate has been studied by x-ray structural analysis. Rings A, B, and C have the chair form and ring D the half-chair form in which the deviations of the atoms from their mean-square plane
Publikováno v:
Chemistry of Natural Compounds. 13:207-210
The interconversions of the alkaloids of Sophora alopecuroides L. have been studied by feeding the plants with tritium-labelled alkaloids ([3H]sophoridine, [3H]pachycarpine, [3H]cytisine, [3H]isosophoridine, [3H]allomatrine, and [3H]N-methylcytisine)
Publikováno v:
Chemistry of Natural Compounds. 17:439-442
A new base — sophorine, with mp 59–60°C, [α]D23-18.9° (c 0.98; ethanol) — has been isolated from the epigeal part of the plantSophora alopecuroides L. Its IR spectrum and the nature of its mass spectrometric composition have permitted sophor
Publikováno v:
Chemistry of Natural Compounds. 17:432-436
In an investigation of the three-dimensional structure of the alkaloid matrine by x-ray structural analysis, a new stereoisomer of it has been detected, which has been called cis-matrine. In cis-matrine rings C and D are cis-linked, while the configu
Publikováno v:
Chemistry of Natural Compounds. 12:696-699
The biosynthesis of the alkaloids ofAmmothamnus lehmannii Bge. have been studied by supplying the plants with [1,5-14C2] cadaverine. It has been shown that cadaverine is a precursor of sophocarpidine, sophocarpine, and pachycarpine. Possible routes o
Publikováno v:
Chemistry of Natural Compounds. 17:340-344
A complete x-ray study of the structure of a stereoisomer of the alkaloid matrine -isosophoridine - has been made. Rings A and B have the cis type of linkage. Rings A, B, and C have the chair form and D the half-chair form.
Publikováno v:
Chemistry of Natural Compounds. 18:66-69
The stereoisomerism of compounds of the matrine series is considered on the basis of the authors' own x-ray structural studies of these alkaloids. A corrected series of eight stereoisomers has been drawn up. It has been shown that the numbers of theo