Zobrazeno 1 - 6
of 6
pro vyhledávání: '"Yu. D. Gavrilov"'
Autor:
V. F. Bystrov, Nikolai S. Zefirov, Yu. D. Gavrilov, N. M. Viktorova, G. M. Nikolaev, S. P. Knyazev
Publikováno v:
Organic Magnetic Resonance. 6:236-239
The vicinal 3Jaa and 3Jee spin-spin coupling constants of a number of deuterated trans-1,2-disubstituted cyclohexenes and the ΔH and ΔS values of the conformational equilibria of these compounds have been determined by computer optimisation of the
Publikováno v:
Journal of Magnetic Resonance (1969). 19:123-129
Tentative angular correlation of the vicinal 13C′NCα1H and 1HCαC′15N coupling constants have been derived from experimental data: 3J(C′NCαH) = 9.0 cos2 θ − 4.4 cos θ − 0.8 (Hz)3J(HCαC′N) = −4.6 cos2 θ + 3.0 cos θ + 0
Publikováno v:
Journal of Magnetic Resonance (1969). 30:151-184
The potentialities of solution-conformational NMR analysis of peptides with fixed (or predominant) structures do not lag behind the X-ray method for crystals. An outstanding merit of NMR spectroscopy is its ability to provide a deep insight into the
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 24:2368-2373
1. The spin-spin interaction constants (SSIC) between1H and13C nuclei were measured for N-methylacetamide and N-acetyl-L-alanine-N-methylamide. 2. The direct and geminal SSIC of13C...1H were calculated for these compounds by a quantum chemical method
Autor:
Vladimir F. Bystrov, V. A. Afanas'ev, S. L. Portnova, S. A. Koz'min, T. A. Balashova, Yu. D. Gavrilov
Publikováno v:
Pure and Applied Chemistry. 36:19-34
An outline is given of some new NMR spectroscopic approaches to the spatial structure of peptides in solution which have been recently suggested and tested in the Shemyakin Institute for Chemistry of Natural Products. The previously derived angular d
Publikováno v:
European journal of biochemistry. 78(1)
The C′= O and Cα signals in the 13C nuclear magnetic resonance (NMR) spectra of valinomycin have been assigned and the vicinal 1H…13C coupling constants have been determined by double and triple heteronuclear resonance. In conjunction with the v