Zobrazeno 1 - 10
of 16
pro vyhledávání: '"Youngmee Jeong"'
Publikováno v:
Tetrahedron Letters. 43:181-184
A new total synthesis of the novel lactone natural product octalactin A is described. The key step involves the facile construction of the eight-membered lactone core via ring-closing metathesis (RCM). This oxocene was elaborated to give the powerful
Autor:
Pedro L. Muino, Nagaaki Sato, Peter C. Still, Indranath Ghosh, Youngmee Jeong, Keith R. Buszek
Publikováno v:
Synthetic Communications. 31:1781-1791
The synthesis of functionalized saturated eight-membered ring lactones from their corresponding seco acids is a very facile process using conventional macrolactonization protocols. This heretofore unrecognized and overlooked strategy is illustrated f
Publikováno v:
Journal of the Chemical Society, Perkin Transactions 1. :1066-1071
Both syn- and anti-[2+2] heterodimers (1 and 2) of methyl phenanthrene-9-carboxylate (9-MP) and benzene were synthesized from 9-MP and cyclohexa-1,4-diene. Upon irradiation of 9-MP and excess methyl orthoformate of cis-cyclohexa-3,5-diene-1,2-diol fo
Publikováno v:
Journal of the Chemical Society, Perkin Transactions 2. :1299-1304
In contrast to the previous report, the irradiation of 9-cyanophenanthrene (9-CP) and furan through a uranium filter yielded an anti-[2+2] adduct (1) as well as the syn-[2+2] cyclodimer (2) of 9-CP. A mechanistic study indicated that the photocycload
Publikováno v:
Journal of the Chemical Society, Perkin Transactions 1. :2501-2504
An unprecedented photodimerization of 1-substituted naphthalenes is reported. Upon irradiation of naphthalene-1-carbonitrile or methyl 1-naphthoate through a Pyrex filter at –78 °C, the corresponding syn-[2+2] cyclodimer was isolated as a single p
Autor:
Keith R. Buszek, Youngmee Jeong
Publikováno v:
Synthetic Communications. 24:2461-2472
The first synthesis of a nine-membered ring by means of an intramolecular Ni(II)/Cr(II)-mediated coupling reaction between an iodoacetylene and an aldehyde is reported. The yield of the reaction is strongly dependent on the substrate concentration, b
Autor:
Youngmee Jeong, Keith R. Buszek
Publikováno v:
ChemInform. 26
The first synthesis of a nine-membered ring by means of an intramolecular Ni(II)/Cr(II)-mediated coupling reaction between an iodoacetylene and an aldehyde is reported. The yield of the reaction is strongly dependent on the substrate concentration, b
Publikováno v:
ChemInform. 25
Autor:
Youngmee Jeong, Keith R. Buszek
Publikováno v:
ChemInform. 26
Pd(0)Cu(I) catalyzed reactions with certain terminal tertiary propargylic alcohols lead to new arylated products. This abnormal cross-coupling pathway represents another example of aryl migration in transition metal catalyzed reactions. The proces
Autor:
Keith R. Buszek, Youngmee Jeong
Publikováno v:
ChemInform. 27
A new and efficient synthesis of the key C.1–C.9 intermediate 5 of the octalactins has been achieved starting from L-ascorbic acid.