Zobrazeno 1 - 10
of 30
pro vyhledávání: '"Yoshitsugu Hasegawa"'
Publikováno v:
Journal of Inclusion Phenomena and Macrocyclic Chemistry. 42:33-38
The intercalation and deintercalation of N, N-dimethyl-1-phenylethylamine (N,N-amine) into α-zirconium phosphate was investigated by pH titration. N,N-amine was taken up easily in one step to give a new phaseZr(HPO4)(HPO4·N,N-amine) · H2O, which w
Publikováno v:
Journal of Inclusion Phenomena and Molecular Recognition in Chemistry. 31:351-355
Crystalline γ-zirconium phenylphosphonate phosphate was prepared according to Yamanaka's method and the intercalation behavior of n-alkylamines and n-alkyldiamines were investigated. In the case of n-alkylamines, a linear increase in interlayer dist
Publikováno v:
Journal of Ion Exchange. 7:2-7
γ-Zirconium phosphate phosphite (γ-ZrPP) was prepared by refluxing γ-zirconium phosphate in 0.1mol⋅dm-3 phosphorous acid according to Alberti's method. Nine n-alkylamines (C3-C14) were employed as guest molecules to intercalate into γ-ZrPP at 2
Publikováno v:
Journal of Inclusion Phenomena and Molecular Recognition in Chemistry. 20:1-12
The uptake of pyridine and quinoline intoα-zirconium phosphate has been investigated by the batch method. The effect of solvent on the reactions was also studied. Pyridine was taken up from ethanol, chloroform, carbon tetrachloride, ethanol-water, a
Publikováno v:
Journal of Inclusion Phenomena and Molecular Recognition in Chemistry. 16:329-337
Intercalation of alkylalcohols into α-zirconium phosphate was investigated at 25°C and/or under reflux.n-Alcohols having two to five carbons and 2-propanol were taken up at 25°C. These alcohols, andn-hexanol and heptanol, also intercalated under r
Publikováno v:
Journal of Inclusion Phenomena and Molecular Recognition in Chemistry. 14:317-326
1,10-Phenanthroline (phen), 2,9-dimethyl-1,10-phenanthroline (neocuproine), and 4,7-dimethyl-1,10-phenanthroline have been intercalated between layers of γ-zirconium phosphate (γ-ZrP). The observed interlayer distances are not a simple function of
Publikováno v:
Journal of Inclusion Phenomena and Molecular Recognition in Chemistry. 10:313-328
The intercalation of phenylethylamines intoα-zirconium phosphate has been investigated by the pH titration method.dl-1-Phenylethylamine (dl-PEA) is taken up in two stages. New phases were obtained: Zr(HPO4)2(dl-PEA) · H2O in the first, and Zr(HPO4)
Publikováno v:
Journal of Inclusion Phenomena and Molecular Recognition in Chemistry. 9:315-325
The ammonium form of γ-zirconium phosphate has been synthesized by the direct precipitation method from fluorozirconate solution in the presence of ammonium dihydrogen phosphate. The hydrogen form Zr(HPO4)2 · 2H2O, was obtained by acid treatment of
Publikováno v:
Bulletin of the Chemical Society of Japan. 56:734-737
The ion-exchange properties of α-zirconium phosphate have been investigated for the H+–[Co(NH3)6]3+ system. The ion-exchange process was examined by means of the variation in the pH values of the supernatant. α-Zirconium phosphate loaded with hex
Autor:
Yoshitsugu Hasegawa, Seiichi Kizaki
Publikováno v:
Chemistry Letters. 9:241-244
The ion-exchange reaction was studied by the batch method at 75 °C. The reaction proceeded in the pH region of 3–6. The analysis of the exchanged solid showed that Co(NH3)63+ exchanged with the protons in the exchanger, and that two phases, the co