Zobrazeno 1 - 6
of 6
pro vyhledávání: '"Yohei Morimasa"'
Autor:
Yusuke Miyake, Tetsuya Taketsugu, Toshimichi Ohmura, Yohei Morimasa, Yasujiro Murata, Tomoya Ichino, Satoshi Maeda, Michinori Suginome, Kunihiko Tajima
Publikováno v:
Bulletin of the Chemical Society of Japan. 94:1894-1902
The mechanism of 4,4'-bipyridine-catalyzed diboration of pyrazines was studied by experimental observation of the inter-mediates and by theoretical calculations. Intermediary radical species were detected by ESR measurement of the reactions of 2,6-di
Publikováno v:
Asian Journal of Organic Chemistry. 8:1092-1096
Publikováno v:
Chemistry Letters. 46:1793-1796
Acetylenedicarboxylates undergo trans-addition of tetraalkoxydiboron in THF at 60 °C in the presence of 4,4′-bipyridine (5 mol %) as a catalyst to give 2,3-diborylfumarates in good yields with high stereoselectivity.
Organocatalytic Diboration Involving 'Reductive Addition' of a Boron–Boron σ-Bond to 4,4′-Bipyridine
Publikováno v:
Journal of the American Chemical Society. 137:2852-2855
A 4,4'-bipyridine-based catalyst system for diboration of pyrazine derivatives was established. The catalyst cycle consists of the following two steps: (1) reductive addition of the boron-boron bond of bis(pinacolato)diboron to 4,4'-bipyridine to for
Publikováno v:
ChemInform. 46
Starting from 4,4′-bipyridines conditions for a scalable reductive two-fold addition of bis(pinacolato)diboron are developed.
Publikováno v:
Journal of the American Chemical Society; 3/4/2015, Vol. 137 Issue 8, p2852-2855, 4p