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Palladium-Catalyzed Double and Single Carbonylations ofβ-Amino Alcohols. Selective Synthesis of Morpholine-2,3-diones and Oxazolidin-2-ones and Applications for Synthesis ofα-Oxo Carboxylic Acids

Autor: Yo Mitsue, Yasushi Imada, Kenichi Washizuka, Shun-Ichi Murahashi, Kazuo Ike

Publikováno v: Bulletin of the Chemical Society of Japan. 69:2079-2090

Catalytic cross double carbonylation of secondary amines and alcohols proceeds in the presence of [PdCl2(MeCN)2] and CuI under carbon monoxide (80 atm) and oxygen (5 atm). Catalytic intramolecular double carbonylation of β-amino alcohols gives morph

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::39c35a6de05570835fce271216432cc7
https://doi.org/10.1246/bcsj.69.2079

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ChemInform Abstract: Palladium-Catalyzed Double and Single Carbonylations of β-Amino Alcohols. Selective Synthesis of Morpholine-2,3-diones and Oxazolidin- 2-ones and Applications for Synthesis of α-Oxo Carboxylic Acids

Autor: Shun-Ichi Murahashi, Yasushi Imada, Kenichi Washizuka, Yo Mitsue, Kazuo Ike

Publikováno v: ChemInform. 27

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::022e438e6af7f36bb0cc1fdc58f3c97d
https://doi.org/10.1002/chin.199642069

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Palladium-Promoted Transformation of β-Amino Ketones to Enaminones

Autor: Tatsuo Tsumiyama, Shun-Ichi Murahashi, Yo Mitsue

Publikováno v: Bulletin of the Chemical Society of Japan. 60:3285-3290

The reaction of β-amino ketones with bis(acetonitrile)dichloropalladium(II) in the presence of triethylamine gives the corresponding enaminones regioselectively. The cyclic β-amino ketones can be converted into the corresponding exocyclic enaminone

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::465d0f6544b1437fdb5b92529390c71b
https://doi.org/10.1246/bcsj.60.3285

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SYNTHESIS OF ENAMINONES BY Pd(II) INDUCED DEHYDROGENATION OF β-AMINO KETONES

Autor: Shun-Ichi Murahashi, Yo Mitsue, Tatsuo Tsumiyama

Publikováno v: Chemistry Letters. 13:1419-1422

The reaction of β-amino ketones with bis(acetonitrile)dichloropalladium(II) in the presence of triethylamine gives enaminones regioselectively.

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::719739ec737c0b320ff381d38c8eeb32
https://doi.org/10.1246/cl.1984.1419

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ChemInform Abstract: SYNTHESIS OF ENAMINONES BY PALLADIUM(II) INDUCED DEHYDROGENATION OF β-AMINO KETONES

Autor: T. Tsumiyama, Shun-Ichi Murahashi, Yo Mitsue

Publikováno v: Chemischer Informationsdienst. 16

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::4bef5bd0ccbee726f2a8ac42155116a2
https://doi.org/10.1002/chin.198507143

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ChemInform Abstract: Palladium-Catalyzed Cross Double Carbonylation of Amines and Alcohols: Synthesis of Oxamates

Autor: Kazuo Ike, Shun-Ichi Murahashi, Yo Mitsue

Publikováno v: ChemInform. 18

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::cb6d6a6d4787efc59902bd5e2b76d205
https://doi.org/10.1002/chin.198727211

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Palladium-catalysed cross double carbonylation of amines and alcohols: synthesis of oxamates

Autor: Kazuo Ike, Yo Mitsue, Shun-Ichi Murahashi

Publikováno v: Journal of the Chemical Society, Chemical Communications. :125

Cross double carbonylation of amines and alcohols in the presence of PdCl2(MeCN)2/Cul catalyst under CO and O2 at room temperature gives oxamates efficiently.

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::97ae41a2a99396999b943091d9f676c6
https://doi.org/10.1039/c39870000125

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