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pro vyhledávání: '"Yesub Keum"'
Publikováno v:
Angewandte Chemie. 132:21775-21780
We present novel titanium-porphyrinic gels (TPGs) and titanium-porphyrinic aerogels (TPAs), in which porphyrinic ligand tetrakis(4-carboxyphenyl)porphyrin is coordinated to Ti-oxo clusters. These hierarchically porous TPAs, with micro-, meso-, and ma
Publikováno v:
Chemical communications (Cambridge, England). 58(5)
Reactive oxygen species (ROS) are highly reactive oxidants that are typically generated by the irradiation of semiconducting materials with visible or UV light and are widely used for the photocatalytic degradation of toxic substances, photodynamic t
Publikováno v:
Inorganic chemistry. 58(23)
Herein, we report titanium-organic gels (TOGs) as new Ti-oxo-based materials that exhibit stimuli-responsive sol-gel transformations and hierarchical porosity upon the removal of solvent molecules. Heating a solution of Ti-oxo clusters and pyromellit
Publikováno v:
Angewandte Chemie (International ed. in English). 57(45)
Titanium(IV)-based metal-organic frameworks (Ti-MOFs) have received significant attention in recent years due to their numerous photocatalytic applications. We herein prepare the single-crystalline Ti-carboxylate MOF (DGIST-1) composed of an unpreced