Zobrazeno 1 - 10
of 97
pro vyhledávání: '"Yasuo Hatanaka"'
Publikováno v:
Chemical Communications. 53:8996-8999
A catalytic enantioselective aza-Diels-Alder reaction of unactivated acyclic dienes with aryl-, alkenyl-, and alkyl-substituted imines is described. With 5-10 mol% loadings of a new Brønsted acid catalyst, the aza-Diels-Alder reaction of unactivated
Publikováno v:
Tetrahedron Letters. 57:2985-2989
Epi-quinine-catalyzed asymmetric nitro-Michael addition of furanones to β,β,-disubstituted nitroalkenes is described. The reaction proceeded smoothly with 1–5 mol % loadings of epi-quinine catalysts at room temperature, giving the corresponding M
Publikováno v:
Organometallics. 32:3575-3582
The synthesis and structures of silaoxazolinium salts 2 and their application to the catalytic Mukaiyama aldol reaction are described. The reaction of (N-amidomethyl)dimethylchlorosilane (1a) or (N-amidomethyl)bis(trimethylsilyl)chlorosilane (1b) wit
Publikováno v:
ChemInform. 47
Epi-quinine-catalyzed asymmetric nitro-Michael addition of furanones to β,β,-disubstituted nitroalkenes is described. The reaction proceeded smoothly with 1–5 mol % loadings of epi-quinine catalysts at room temperature, giving the corresponding M
Publikováno v:
ChemInform. 47
Catalyst-controlled switching of diastereoselectivity from high syn-selectivity (>98/2 dr, syn) to anti-selectivity (up to 96/4 dr, anti) of the asymmetric nitro-Michael reaction of furanones is described. Anti-diastereoselectivity of the nitro-Micha
Publikováno v:
Organic letters. 18(4)
Catalyst-controlled switching of diastereoselectivity from high syn-selectivity (>98/2 dr, syn) to anti-selectivity (up to 96/4 dr, anti) of the asymmetric nitro-Michael reaction of furanones is described. Anti-diastereoselectivity of the nitro-Micha
Publikováno v:
ChemInform. 46
A novel epi-quinine-derived organocatalyst is applied to the asymmetric nitro-Michael reaction of furanones, giving the Michael adducts in remarkably high diastereo- and enantioselectivity.
Publikováno v:
Organic letters. 17(12)
High catalytic activity of novel epi-quinine-derived 3,5-bis(CF3)benzamide in the asymmetric nitro-Michael reaction is described. With 0.1-5 mol % loadings of this catalyst, the addition of 5-substituted 2(3-H)-furanones to a wide range of nitroalken
Autor:
Yasuo Hatanaka
Publikováno v:
Journal of Organometallic Chemistry. 685:207-217
Synthesis, structures, and electronic properties of silicon polymers and oligomers having hypervalent silicon moieties, polar substituents, or transition metal moieties are reported. UV spectra of pentacoordinate silicon oligomers reveal that the int
Publikováno v:
ChemInform. 45
NMR Studies reveal that chiral pentacoordinate silyl triflimides derived from BINOL derivatives (I) with a silicon stereogenic center are highly configurationally unstable.