Zobrazeno 1 - 5
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pro vyhledávání: '"Yantrapragada Suseela"'
Publikováno v:
Tetrahedron. 51:2743-2748
Addition of RMgX and BrMg (CH 2 ) nMgBr reagents to alkenylcatecholborane followed by iodine induced rearrangement and oxidation provided Z-olefins and Z-olefinic alcohols in moderate to good yields. This procedure is advantageous over the previous m
Publikováno v:
ChemInform. 23
Reaction of aliphatic carboxylic acids (1 eq) using NaBH4 (2 eq) and catechol (2 eq) in THF at 25°C gives the corresponding alcohols in 47–49% yield besides the unreacted carboxylic acids. Reduction of aliphatic carboxylic acids (1 eq) using NaBH4
Publikováno v:
ChemInform. 26
Publikováno v:
Tetrahedron. 48:371-376
Reaction of aliphatic carboxylic acids (1 eq) using NaBH4 (2 eq) and catechol (2 eq) in THF at 25°C gives the corresponding alcohols in 47–49% yield besides the unreacted carboxylic acids. Reduction of aliphatic carboxylic acids (1 eq) using NaBH4
Publikováno v:
Journal of the Chemical Society, Chemical Communications. :446
Alkenyl catecholboranes are readily formed by the reaction of catecholborane and alk-1-ynes at 25°C, in the presence of 10 mol% of a BH3:N,N-diethylaniline complex, via a hydroboration–alkenyl transfer mechanism.