Zobrazeno 1 - 10
of 13
pro vyhledávání: '"Yangzhen Ciringh"'
Publikováno v:
Inorganica Chimica Acta. 294:133-139
The oxidation of (3,3′-17-crown-6-SALPN)Mn(II) with O 2 in CH 3 CN resulted in formation of the corresponding Mn(IV),Mn(IV) bis(μ-oxo) dimer ( 2 ). A 16 O 2 / 18 O 2 labeling experiment, in which the product was analyzed by FT-IR spectroscopy and
Publikováno v:
Chemistry of Materials. 11:2974-2983
The synthesis of diarylethyne-linked multiporphyrin arrays requires Pd-mediated coupling conditions that are performed in dilute solution in the absence of copper and that give reaction mixtures that are easily purified. We previously developed coppe
Autor:
Jonathan S. Lindsey, Charles H. Martin, Feirong Li, Robert R. Birge, Dongho Kim, Dewey Holten, Jyoti Seth, Sung Ik Yang, David F. Bocian, Yangzhen Ciringh, Deepak Singh
Publikováno v:
Journal of the American Chemical Society. 120:10001-10017
Light-harvesting arrays containing one, two, or eight boron-dipyrrin (BDPY) pigments and one porphyrin (free base or Zn chelate) have been synthesized using a modular building block approach. The reaction of pyrrole and 4-(BDPY)benzaldehyde or 3,5-bi
Autor:
Yangzhen Ciringh, Jonathan S. Lindsey
Publikováno v:
Journal of Chromatography A. 816:251-259
Sugar phosphates and related compounds can be rapidly separated using capillary zone electrophoresis and quantitated via indirect UV detection using potassium sorbate at 256 nm. Three buffers were examined at various pH values. The optimum separation
Autor:
Colin P. Horwitz, George R. Clark, Richard E. Norman, Susan T. Weintraub, Scott W. Gordon-Wylie, Yangzhen Ciringh
Publikováno v:
Inorganic Chemistry. 36:4968-4982
The 1H NMR spectra of symmetrically substituted paramagnetic [(R,R‘-SALOPHEN)MnIII]+ and [(R,R‘-SALOPHEN)MnIII]2(μ-O) complexes (SALOPHEN is 1,3-bis(salicylideneamino)benzene) were obtained. All of the monomers and dimers yielded well-resolved b
Autor:
Michael C.W. Evans, Yangzhen Ciringh, Colin P. Horwitz, Susan T. Weintraub, Joseph T. Warden, Jonathan H. A. Nugent, Sandra Turconi
Publikováno v:
Le Journal de Physique IV. 7:C2-603
A complex containing four manganese centres is thought to be the catalytic site of photosynthetic water oxidation. The structure and mechanism of action of this complex are largely unknown. Mn-coordination complexes can be used as models for the mang
Autor:
Susan T. Weintraub, Yangzhen Ciringh, Colin P. Horwitz, Joseph T. Warden, Michael C.W. Evans, Jonathan H. A. Nugent, Sandra Turconi
Publikováno v:
Journal of the Chemical Society, Dalton Transactions. :4075-4082
An X-ray absorption spectroscopic study was made of seven different manganese co-ordination compounds, six of which are dinuclear and contain the structural bis(µ-oxo) unit. In all the compounds each manganese is ligated by one crown ether Schiff-ba
Autor:
Yangzhen Ciringh, Colin P. Horwitz
Publikováno v:
Inorganica Chimica Acta. 225:191-200
The dimer [( 1 )Mn III ] 2 (μ-O) ( 3 ) was synthesized by oxygenation of the mononuclear Mn(II) complex in CH 3 CN. The ligand used was 3,3′-17-crown-6-SAL-3-CH 3 -OPHEN ( 1 ). Dimer 3 reacted with KPF 6 and Ba(SO 3 CF 3 ) 2 in DMF forming 3 ·2KP
Publikováno v:
Inorganic Chemistry. 32:5951-5956
The bis(μ-oxo) dimers [(X-SALPRN)Mn IV (μ-O)] 2 , where X=5-Cl, 1c, 3,5-Cl 2 , 2c, and 5-CH 3 O, 3c, and SALPRN is 1,3-bis(salicylideneamino)propane, were prepared by two routes: oxidation of (X-SALPRN)Mn II , X=5-Cl, 1b, 3,5-Cl 2 , 2b, and 5-CH 3
Publikováno v:
Chemistry of Materials. 4:827-832
Steady-state fluorescence anisotropy is shown to monitor the mobility of a small molecule in a plasticzed polymer membrane and yields in formation about the microviscosity in the membrane. The technique was applied to a valinomycin based neutral-carr