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Publikováno v:
Catal. Sci. Technol.. 4:1914-1919
A multicatalytic system composed of copper complexes and sec-amine compounds is proposed for γ-oxyamination of α,β-unsaturated aldehydes. Using copper complexes in dienamine catalysis expands the scope of the reaction to include TEMPO radicals. Fu
Publikováno v:
European Journal of Organic Chemistry. 2012:5655-5659
The combination of a copper complex and a chiral amine organocatalyst induces the formation of multifunctionalized aldehydes from aromatic and aliphatic allylic alcohols. Reactions occur with excellent levels of enantioselectivity, under environmenta
Publikováno v:
Organic Letters. 14:3272-3275
A remarkably efficient photosensitizer, N719 dye, was used in asymmetric tandem Michael addition/oxyamination of aldehydes, rendering α,β-substituted aldehydes in good yields with excellent levels of enantioselectivity and diastereoselectivity. Thi
Publikováno v:
European Journal of Organic Chemistry. 2009:5309-5312
Electrochemical oxidation was performed during the organocatalyzed α-oxyamination of aldehydes by using a one-compartment electrolytic cell under galvanostatic conditions. In the presence of substoichiometric amounts of sec-amines, the desired coupl
Publikováno v:
Bulletin of the Korean Chemical Society. 29:1624-1626
To improve the activity of dirhodium complexes in thecatalytic reactions or biological reactions, a variety ofligands can be employed not only at the axial position butalso at the bridging position of dirhodium complexes. Sinceligands at either bridg
Autor:
Pilsoo Kim, Hye-Young Jang, Ju-Hye Kim, Xuan-Huong Ho, Hoseop Yun, Eun-Jin Park, Hyo-Sang Yoon, Hwa-Jung Lee
Publikováno v:
ChemInform. 44
The title reaction proceeds through iminium-catalyzed Michael addition followed by copper-assisted addition of TEMPO in a one-pot manner.
Publikováno v:
ChemInform. 44
A one-pot oxidation/Michael addition/oxamination reaction of allylic alcohols affords the formation of multifunctionalized aldehydes with high levels of stereoselectivity under environmentally benign conditions.
Publikováno v:
ChemInform. 43
In the presence of an optimized chiral organocatalyst and TiO2, aldehydes with TEMPO to give the corresponding α-piperidinyloxy-substituted aldehydes in a highly chemo- and stereoselective manner.
Publikováno v:
European Journal of Organic Chemistry.
The asymmetric organocatalyzed α-alkylation of aldehydes via a cationic radical enamine intermediate was performed under environmentally benign electro-oxidation conditions without the use of chemical oxidants. To promote the desired α-alkylation r