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pro vyhledávání: '"Xuan B. Nguyen"'
Autor:
David W. Lupton, Martin Breugst, Yuji Nakano, Lydia Scott, Nisharnthi M. Duggan, Xuan B. Nguyen
Publikováno v:
Angewandte Chemie International Edition. 58:11483-11490
Direct polarity inversion of conjugate acceptors provides a valuable entry to homoenolates. N-heterocyclic carbene (NHC) catalyzed reactions, in which β-unsubstituted conjugate acceptors undergo homoenolate formation and C-C bond formation twice, ha
Autor:
Andrew D. Smith, James E. Taylor, Anastassia Matviitsuk, David W. Lupton, Alexandra M. Z. Slawin, Xuan B. Nguyen, Mark D. Greenhalgh, David B. Cordes
Publikováno v:
Matviitsuk, A, Greenhalgh, M D, Taylor, J E, Nguyen, X B, Cordes, D B, Slawin, A M Z, Lupton, D W & Smith, A D 2020, ' Unanticipated Silyl Transfer in Enantioselective α,β-Unsaturated Acyl Ammonium Catalysis Using Silyl Nitronates ', Organic Letters, vol. 22, no. 1, pp. 335-339 . https://doi.org/10.1021/acs.orglett.9b04404
We thank the European Research Council under the European Union’s Seventh Framework Programme (FP7/2007–2013), ERC Grant Agreement 279850 (A.D.S.), the EPSRC (EP/J018139/1, A.M.), and the Royal Society of Chemistry (Researcher Mobility Grant). A.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::17935d71772faa26aa9a754853c06e0e
https://purehost.bath.ac.uk/ws/files/205649548/ITU_Silyl_Nitronates_Revised_Manuscript_Accepted.docx
https://purehost.bath.ac.uk/ws/files/205649548/ITU_Silyl_Nitronates_Revised_Manuscript_Accepted.docx
Publikováno v:
Australian Journal of Chemistry. 73:1
Polarity inversion is the hallmark of N-heterocyclic carbene (NHC) organocatalysis, with the generation and reaction of acyl anion equivalents known for more than 70 years. In contrast, polarity inversion through 1,4-addition of NHCs to conjugate acc