Distinct electronic structures and bonding interactions in inverse-sandwich samarium and ytterbium biphenyl complexes

Autor: Xiao, Yuyuan, Zhao, Xiao-Kun, Wu, Tianpin, Miller, Jeffrey T, Hu, Han-Shi, Li, Jun, Huang, Wenliang, Diaconescu, Paula L

Publikováno v: Chemical science, vol 12, iss 1

Inverse-sandwich samarium and ytterbium biphenyl complexes were synthesized by the reduction of their trivalent halide precursors with potassium graphite in the presence of biphenyl. While the samarium complex had a similar structure as previously re

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=od_______325::a5819b1fa6db15d2b3fcd264bc278268
https://escholarship.org/uc/item/18x8x2gq

Tento výsledek nelze pro nepřihlášené uživatele zobrazit.
K zobrazení výsledku je třeba se přihlásit.

Distinct electronic structures and bonding interactions in inverse-sandwich samarium and ytterbium biphenyl complexes.

Autor: Xiao Y; Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Material Chemistry and Application, College of Chemistry and Molecular Engineering, Peking University Beijing 100871 P. R. China wlhuang@pku.edu.cn., Zhao XK; Department of Chemistry and Key Laboratory of Organic Optoelectronics & Molecular Engineering of the Ministry of Education, Tsinghua University Beijing 100084 P. R. China hshu@mail.tsinghua.edu.cn., Wu T; Chemical Sciences and Engineering Division, Argonne National Laboratory Argonne Illinois 60439 USA., Miller JT; Chemical Sciences and Engineering Division, Argonne National Laboratory Argonne Illinois 60439 USA., Hu HS; Department of Chemistry and Key Laboratory of Organic Optoelectronics & Molecular Engineering of the Ministry of Education, Tsinghua University Beijing 100084 P. R. China hshu@mail.tsinghua.edu.cn., Li J; Department of Chemistry and Key Laboratory of Organic Optoelectronics & Molecular Engineering of the Ministry of Education, Tsinghua University Beijing 100084 P. R. China hshu@mail.tsinghua.edu.cn., Huang W; Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Material Chemistry and Application, College of Chemistry and Molecular Engineering, Peking University Beijing 100871 P. R. China wlhuang@pku.edu.cn., Diaconescu PL; Department of Chemistry and Biochemistry, University of California Los Angeles California 90095 USA pld@chem.ucla.edu.

Publikováno v: Chemical science [Chem Sci] 2020 Oct 29; Vol. 12 (1), pp. 227-238. Date of Electronic Publication: 2020 Oct 29.