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Autor:
Xaiohan Li, Ruchita R. Thakore, Gianluca Casotti, Fabrice Gallou, Balaram S. Takale, Bruce H. Lipshutz
Publikováno v:
Angewandte Chemie International Edition. 60:4158-4163
An inexpensive and new triphenylphosphine-based palladacycle has been developed as a pre-catalyst, leading to highly effective Stille cross-coupling reactions in water under mild reaction conditions. Only 500-1000 ppm of Pd suffices for couplings inv