Zobrazeno 1 - 10
of 118
pro vyhledávání: '"Wolfram Grimme"'
Publikováno v:
Angewandte Chemie. 93:98-103
Publikováno v:
Journal of the Chemical Society, Perkin Transactions 2. :1959-1965
The cheletropic ene-reaction is presented as an extension of the known pericyclic additions. No example of this process is known but some decarbonylations have been discussed as its reverse. The scope of these reactions is extended by the facile deca
Publikováno v:
Synlett. 1998:1175-1181
Publikováno v:
Journal of the Chemical Society, Perkin Transactions 2. :1893-1900
The all-syn oligocondensed bicyclo[2.2.2]octenes 3, 5, 20 and 29 with two to five etheno bridges show interaction of their π-orbitals by σ-overlap. This laticyclic conjugation reveals itself in the PE and UV spectra of the series as well as in the
Autor:
Wolfram Grimme, Susanne Krauthäuser
Publikováno v:
Tetrahedron. 53:9903-9912
Tetracyclo[7.3.1.0 2,8 .0 4,12 ]trideca-5,10-diene ( 3 ) is synthesized and partially resolved via reversible ligand exchange in its 4 η-diene-tfacac-rhodium(I) complexes 10 and 11 with the C 2 -chiral bidentate bis-[4(R)-methyl- 5(R)-phenyloxazolin
Publikováno v:
Journal of the Chemical Society, Perkin Transactions 2. :1955-1958
The tetrahydro[4]beltene 8 has been synthesized via a sequence of three Diels–Alder reactions. As shown in the crystal structure of 8, the two double bonds in the cage diene are positioned face-to-face at a distance of 2.92 A, which is smaller than
Publikováno v:
Liebigs Annalen. 1996:1905-1916
Dyotropic Hydrogen Transfer in Dihydrosesqui- and in Dihydro-syn-sesterbicyclo[2.2.2]octenes The intramolecular dyotropic hydrogen transfer is studied in dihydrosesquibicyclo[2.2.2]octenes. In the parent system 4-d2 the process transfers two hydrogen
Publikováno v:
ChemInform. 22
Publikováno v:
ChemInform. 23
Publikováno v:
ChemInform. 23