Zobrazeno 1 - 10
of 33
pro vyhledávání: '"Wolfgang Kühnle"'
Autor:
Attila Demeter, Seiji Tobita, Haruo Shizuka, Klaas A. Zachariasse, Kengo Suzuki, Erich Tauer, Wolfgang Kühnle
Publikováno v:
Physical Chemistry Chemical Physics. 2:981-991
The thermally activated internal conversion (IC) taking place in 4-substituted 1-(dimethylamino)naphthalenes (14DMX) and 1-aminonaphthalenes (14ANX) with X=CN, Cl, H, CH3 and OCH3 was investigated in three solvents spanning the polarity scale, hexane
Autor:
Klaas A. Zachariasse, Erich Tauer, Olaf Morawski, Wolfgang Kühnle, Attila Demeter, Ingo Rückert
Publikováno v:
The Journal of Physical Chemistry A. 103:1958-1966
With the 1-aminonaphthalenes 1N5 and 1DMAN a fast radiationless process occurs in n-hexane, diethyl ether, and acetonitrile, which is shown to be internal conversion (IC). The IC reaction is slower with 1N4 and much less efficient with 1MAN and 1AN.
Publikováno v:
Chemical Physics Letters. 282:7-15
To address the issue of electronic interaction between donor (D) and acceptor (A) moieties in intramolecular charge transfer reactions a series of chemically closely related extended π-systems has been investigated. These compounds contain pyrene an
Publikováno v:
The Journal of Physical Chemistry A. 101:7043-7046
Magnetic field effects (MFE) detected by intramolecular exciplex fluorescence have been studied in acetonitrile solutions for new donor−acceptor compounds in which pyrene is linked to aza-15-crown ether by a polymethylene chain with 3, 9, and 16 CH
Autor:
Wolfgang Kühnle, Klaas A. Zachariasse, I. Rückert, A. Hebecker, Th. von der Haar, O. Morawski, M. Grobys, Yu.V. Il'ichev
Publikováno v:
Journal of Photochemistry and Photobiology A: Chemistry. 105:373-383
A discussion is presented of the fast excited state intramolecular charge transfer (ICT) and dual fluorescence observed with several 4-aminobenzonitriles. The occurrence or absence of this ICT reaction is shown to be determined by the magnitude of th
Publikováno v:
Chemical Physics. 211:441-453
The fluorescence decays of trans-4-dimethylamino-4′-cyanostilbene (DCS) and trans-4-azetidinyl-4′-cyanostilbene (ACS) in an unpolar (n-heptane) and a polar (acetonitrile) solvent are single exponential down to a time resolution of around 5 ps and
Publikováno v:
Journal of Photochemistry and Photobiology A: Chemistry. 85:77-83
The influence of external magnetic fields on the spin dynamics and recombination reaction yield of radical ion pairs, generated by photoinduced electron transfer between pyrenyl and dimethylaniline linked by an oligopeptide bridge, was studied. From
Publikováno v:
Journal of Fluorescence. 4:87-90
A spectro-streak photometer, an instrument for simultaneously measuring fluorescence intensity, time, and wavelength,I(t, λ), with a single picosecond excitation pulse, has been constructed. Two typical and currently highly topical examples of mesur
Publikováno v:
Journal of Photochemistry and Photobiology A: Chemistry. 70:83-93
Time-resolved transient absorption (TRABS) experiments were carried out on a picosecond to nanosecond time scale in order to determine the mechanism of photoinduced hydrogen transfer between benzophenone (Bp) and dimethylaniline (DMA) covalently link
Publikováno v:
Pure and Applied Chemistry. 65:1745-1750
Dual fluorescence and intramolecular charge transfer (ICT) are observed with aminobenzonitriles when two excited state levels (S 1 and S 2 (CT) in DMABN) have an energy gap sufficiently small for vibronic coupling: a solvent-induced pseudo-Jahn-Telle