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pro vyhledávání: '"Wojciech, Karpiesiuk"'
Autor:
Wojciech Karpiesiuk, Anna Banaszek
Publikováno v:
Carbohydrate Research. 299:245-252
The synthesis of the title compounds is described, i.e. coupling of the ylide, generated from the iodophosphonium salt of protected N-phthaloyl-D-galactosamine with 2,3-O-isopropylidene D-ribo-aldehyde afforded an undecose in high yield. Hydroboratio
Publikováno v:
Carbohydrate Research. 257:25-33
The structures of the title compounds 2b and 3) have been investigated in the solid state by X-ray methods. The crystals of 2b are monoclinic, space group P21, and of 3 orthorhombic, space group P212121. The cell dimensions are: for 2b, a = 9.910(2),
Autor:
Anna Banaszek, Wojciech Karpiesiuk
Publikováno v:
Tetrahedron. 50:2965-2974
A five-step synthesis of deaminotunicaminyluracil is presented. Coupling of the ylide, generated from the phosphonium salt 4, with the aldehyde 5 afforded the undecose 6 in high yield. The key step in this synthesis was the hydroboration-oxidation re
Autor:
Anna Banaszek, Wojciech Karpiesiuk
Publikováno v:
Carbohydrate Research. 251:233-242
Reduction of the title compounds of types 1 and 2 under mild conditions using LiBH 4 -Me 3 SiCl species, followed by acetylation, yielded the corresponding 2-amino sugars of α- d - gluco ( 5 ) and β- d - manno ( 6 ) configuration, respectively, wit
Autor:
Wojciech Karpiesiuk, Anna Banaszek
Publikováno v:
Bioorganic & Medicinal Chemistry Letters. 4:879-882
The title compound 9 was synthesized by Wittig reaction of phosphonium salt 6 with aldehyde 7 to afford Z-olefin 8 , with subsequent following hydration via a hydroboration-oxidation process.
Autor:
Anna Banaszek, Wojciech Karpiesiuk
Publikováno v:
ChemInform. 25
A five-step synthesis of deaminotunicaminyluracil is presented. Coupling of the ylide, generated from the phosphonium salt 4, with the aldehyde 5 afforded the undecose 6 in high yield. The key step in this synthesis was the hydroboration-oxidation re
Autor:
Wojciech Karpiesiuk, Anna Banaszek
Publikováno v:
ChemInform. 25
Reduction of the title compounds of types 1 and 2 under mild conditions using LiBH 4 -Me 3 SiCl species, followed by acetylation, yielded the corresponding 2-amino sugars of α- d - gluco ( 5 ) and β- d - manno ( 6 ) configuration, respectively, wit
Autor:
Anna Banaszek, Wojciech Karpiesiuk
Publikováno v:
ChemInform. 26
3,4,6-Tri- O -benzoyl-2-(benzoyloxyimino)-2-deoxy-α- d - arabino -hexopyranosyl bromide ( 2 ) reacts with the O -protected 2-deoxy-2-phthalimido-β- d -galactosamines 3 and 4 in the presence of silver triflate and sym -collidine at −78°C, to give
Autor:
Wojciech Karpiesiuk, Anna Banaszek
Publikováno v:
ChemInform. 28
The synthesis of the title compounds is described, i.e. coupling of the ylide, generated from the iodophosphonium salt of protected N-phthaloyl-D-galactosamine with 2,3-O-isopropylidene D-ribo-aldehyde afforded an undecose in high yield. Hydroboratio
Autor:
Anna Banaszek, Wojciech Karpiesiuk
Publikováno v:
Journal of Carbohydrate Chemistry. 9:909-914
Among the known non-symmetrical naturally occurring aminotrehaloses possessing antimicrobial activity, the stereoselective synthesis of α, α-linked D-glucosaminyl-D-glucoside as well as of D-glucosaminyl-D-mannoside has been reported.1 In contrast,