Zobrazeno 1 - 10
of 25
pro vyhledávání: '"Wing Y. Man"'
Publikováno v:
Acta Crystallographica Section E, Vol 70, Iss 12, Pp 462-465 (2014)
In the title compound, C4H22B20, the two {1,2-closo-C2B10H11} cages are linked across a centre of inversion with a C—C distance of 1.5339 (11) Å. By careful analysis of the structure, it is established that the non-linking cage C atom is equally d
Externí odkaz:
https://doaj.org/article/d6023d3c0bf84e648883b9a87a5ede94
Publikováno v:
Acta Crystallographica Section E: Crystallographic Communications, Vol 71, Iss 7, Pp m141-m142 (2015)
A new polymorph of the title compound 2-(η-C5H5)-2,1,7-closo-CoC2B9H11, [Co(C5H5)(C2H11B9)], in the space group P21/n has been characterized, including the unambiguous location of both cage C atoms. The precision of this study is an order of magnitu
Externí odkaz:
https://doaj.org/article/f0a972bdf99d4f48b13ba2370080870c
Autor:
John Jones, Alan J. Welch, Wing Y. Man, Greig Scott, Nicholas A. Beattie, Stuart MacGregor, Alasdair Robertson, Georgina Margaret Rosair
Publikováno v:
Angewandte Chemie International Edition. 55:8706-8710
Three isomers of [(Cp*Ru)2 C2 B10 H12 ], the first examples of 14-vertex heteroboranes containing 14-skeletal electron pairs, have been synthesized by the direct electrophilic insertion of a {Cp*Ru(+) } fragment into the anion [4-Cp*-4,1,6-RuC2 B10 H
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::405a7138463b8eaa13823921b3d535ce
https://doi.org/10.1002/anie.201602440
https://doi.org/10.1002/anie.201602440
Publikováno v:
Angewandte Chemie International Edition. 55:4596-4599
Two-electron reduction of 1,1'-bis(o-carborane) followed by reaction with [Ru(η-mes)Cl2 ]2 affords [8-(1'-1',2'-closo-C2 B10 H11 )-4-(η-mes)-4,1,8-closo-RuC2 B10 H11 ]. Subsequent two-electron reduction of this species and treatment with [Ru(η-are
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::425dd2b4db6f7d6b0864e03981a3f26f
https://doi.org/10.1002/anie.201600635
https://doi.org/10.1002/anie.201600635
Autor:
Wing Y. Man, Alan J. Welch, Laura E. Riley, Antony P. Y. Chan, Igor B. Sivaev, James Taylor, David Ellis, Georgina M. Rosair
Publikováno v:
Dalton Transactions. 45:1127-1137
Doubly-deprotonated 1,1'-bis(o-carborane) reacts with [RuCl2(p-cymene)]2 to afford [Ru(κ3-2,2',3'-{1-(1'-1',2'-closo-C2B10H10)-1,2-closo-C2B10H10})(p-cymene)] (1) in which 1,1'-bis(o-carborane) acts as an X2-(C,C')L ligand where "L" is a B3'–H3'
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2cb8a167d8a7a12b2d8eda15652061a0
https://doi.org/10.1039/c5dt03417e
https://doi.org/10.1039/c5dt03417e
Autor:
David Ellis, Alan J. Welch, Georgina M. Rosair, Louise Schaefer, Wing Y. Man, Samuel L. Powley
Publikováno v:
Dalton Transactions. 45:3635-3647
The new nitrosocarboranes [1-NO-2-R-1,2-closo-C2B10H10] [R = CH2Cl (1), CH3OCH2 (2) p-MeC6H4 (3), SiMe3 (4) and SiMe2tBu (5)] and [1-NO-7-Ph-1,7-closo-C2B10H10] (6) were synthesised by reaction of the appropriate lithiocarborane in diethyl ether with
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6d68fca66e27e0b22320ebbb2a371399
https://doi.org/10.1039/c5dt04831a
https://doi.org/10.1039/c5dt04831a
Publikováno v:
Journal of Organometallic Chemistry. 798:36-40
The compounds (dmpe)Ni{κ2-2,2′-[1-(1′-1′,2′-closo-C2B10H10)-1,2-closo-C2B10H10]} (1) and (dppe)Ni{κ2-2,2′-[1-(1′-1′,2′-closo-C2B10H10)-1,2-closo-C2B10H10]} (2) have been synthesised and fully characterised, including crystallographi
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::81896180acb9af1760c420828ea7cf00
https://doi.org/10.1016/j.jorganchem.2015.04.011
https://doi.org/10.1016/j.jorganchem.2015.04.011
Publikováno v:
Journal of Organometallic Chemistry. 792:51-54
The structures of 1,2-μ-(C4H6)-1,2-closo-C2B10H10 (“dihydrobenzocarborane”) and 1,2-μ-(C4H4)-1,2-closo-C2B10H10 (“benzocarborane”) determined previously (Wade et al., 1996) are analysed. This provides evidence for an enhanced structural car
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::73ddde9eae9ada58d3be889d3916d4ee
https://doi.org/10.1016/j.jorganchem.2015.01.004
https://doi.org/10.1016/j.jorganchem.2015.01.004
Publikováno v:
Acta Crystallographica Section C Structural Chemistry. 71:793-798
Bothrac-[1-(1′-4′-Cp-4′,1′,12′-closo-CoC2B10H11)-4-Cp-4,1,12-closo-CoC2B10H11]·2THF (Cp is cyclopentadienyl and THF is tetrahydrofuran) or [Co2(C5H5)2(C4H22B20)]·2C4H8O, (1), andmeso-[1-(1′-4′-Cp-4′,1′,12′-closo-CoC2B10H11)-4-Cp
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::3ab2b004eee0a86d952a9a7af20e032b
https://doi.org/10.1107/s2053229615014539
https://doi.org/10.1107/s2053229615014539
Autor:
David Ellis, David McKay, Stuart MacGregor, Cesar Palmero, Antony P. Y. Chan, Laure Jourdan, Bernhard T. Leube, Alan J. Welch, Wing Y. Man, Gobika Thiripuranathar, Georgina M. Rosair
Publikováno v:
Dalton Transactions. 44:5628-5637
Examples of singly-metallated derivatives of 1,1'-bis(o-carborane) have been prepared and spectroscopically and structurally characterised. Metallation of [7-(1'-1',2'-closo-C2B10H11)-7,8-nido-C2B9H10](2-) with a {Ru(p-cymene)}(2+) fragment affords b
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::fe8c2f17d085f9fa53f625a4a974ef90
https://doi.org/10.1039/c5dt00081e
https://doi.org/10.1039/c5dt00081e