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pro vyhledávání: '"Winfried Golla"'
Autor:
Winfried Golla, Karin Wichmann, Duc Le Van, Gernot Frenking, Bernt Krebs, Mechtild Läge, Nikolaus Fröhlich, Joseph Grobe
Publikováno v:
Organometallics. 21:2921-2930
The syntheses of the phosphane complexes M(CO)5PH3 (M = Mo, W), W(CO)5PD3, and W(CO)5PF3 and the results of X-ray structure analyses of W(CO)5PH3 and Mo(CO)5PCl3 are reported. Quantum-chemical DFT calculations of the geometries and M−P bond dissoci
Publikováno v:
Organometallics. 17:5717-5720
Isolable mono(metallo)stibanes of the type [M]Sb(CF3)2 ([M] = (CO)5Mn (3a), (CO)5Re (3b), Cp(CO)3Cr (3c), Cp(CO)3Mo (3d), C5Me5(CO)3W (3e)) are formed quantitatively by reactions of Sb(CF3)3 (1) with the corresponding hydride complexes [M]H (2) with