Spin propensity in resonant photoemission of transition metal complexes

Autor: Robert H. Temperton, Wilson Quevedo, Robert Seidel, Jens Uhlig, Joachim Schnadt, Petter Persson

Publikováno v: Physical Review Research, Vol 3, Iss 3, p 033030 (2021)

Resonant photoelectron spectroscopy (RPES) has been used to probe electronic structure properties of the closed-shell [Fe^{II}(CN)_{6}]^{4−} and open-shell [Fe^{III}(CN)_{6}]^{3−} prototype transition metal complexes in aqueous solution. Site-sel

Externí odkaz: https://doaj.org/article/405d91a5016248c1b624715999813357

Soft x-ray absorption spectroscopy of metalloproteins and high-valent metal-complexes at room temperature using free-electron lasers

Autor: Markus Kubin, Jan Kern, Sheraz Gul, Thomas Kroll, Ruchira Chatterjee, Heike Löchel, Franklin D. Fuller, Raymond G. Sierra, Wilson Quevedo, Christian Weniger, Jens Rehanek, Anatoly Firsov, Hartawan Laksmono, Clemens Weninger, Roberto Alonso-Mori, Dennis L. Nordlund, Benedikt Lassalle-Kaiser, James M. Glownia, Jacek Krzywinski, Stefan Moeller, Joshua J. Turner, Michael P. Minitti, Georgi L. Dakovski, Sergey Koroidov, Anurag Kawde, Jacob S. Kanady, Emily Y. Tsui, Sandy Suseno, Zhiji Han, Ethan Hill, Taketo Taguchi, Andrew S. Borovik, Theodor Agapie, Johannes Messinger, Alexei Erko, Alexander Föhlisch, Uwe Bergmann, Rolf Mitzner, Vittal K. Yachandra, Junko Yano, Philippe Wernet

Publikováno v: Structural Dynamics, Vol 4, Iss 5, Pp 054307-054307-16 (2017)

X-ray absorption spectroscopy at the L-edge of 3d transition metals provides unique information on the local metal charge and spin states by directly probing 3d-derived molecular orbitals through 2p-3d transitions. However, this soft x-ray techniqu

Externí odkaz: https://doaj.org/article/e62ed1004aa64887bad7492842ed8011

A liquid flatjet system for solution phase soft-x-ray spectroscopy

Autor: Maria Ekimova, Wilson Quevedo, Manfred Faubel, Philippe Wernet, Erik T. J. Nibbering

Publikováno v: Structural Dynamics, Vol 2, Iss 5, Pp 054301-054301-13 (2015)

We present a liquid flatjet system for solution phase soft-x-ray spectroscopy. The flatjet set-up utilises the phenomenon of formation of stable liquid sheets upon collision of two identical laminar jets. Colliding the two single water jets, coming o

Externí odkaz: https://doaj.org/article/cac4c21555324565ba14460ce118824c

Anti-Stokes resonant x-ray Raman scattering for atom specific and excited state selective dynamics

Autor: Kristjan Kunnus, Ida Josefsson, Ivan Rajkovic, Simon Schreck, Wilson Quevedo, Martin Beye, Sebastian Grübel, Mirko Scholz, Dennis Nordlund, Wenkai Zhang, Robert W Hartsock, Kelly J Gaffney, William F Schlotter, Joshua J Turner, Brian Kennedy, Franz Hennies, Simone Techert, Philippe Wernet, Michael Odelius, Alexander Föhlisch

Publikováno v: New Journal of Physics, Vol 18, Iss 10, p 103011 (2016)

Ultrafast electronic and structural dynamics of matter govern rate and selectivity of chemical reactions, as well as phase transitions and efficient switching in functional materials. Since x-rays determine electronic and structural properties with e

Externí odkaz: https://doaj.org/article/18009923150c4edcae6855b83689d99f

Near-Ambient Pressure XPS and NEXAFS Study of a Superbasic Ionic Liquid with CO2

Autor: Karen L. Syres, David C. Grinter, Andrew G. Thomas, Claudia L. Compean-Gonzalez, Federica Venturini, Jordan Cole, Christopher Hardacre, Adam J. Greer, Georg Held, Zoë Henderson, Pilar Ferrer, Wilson Quevedo Garzon

Publikováno v: Cole, J, Henderson, Z, Thomas, A G, Compeán-gonzález, C L, Greer, A J, Hardacre, C, Venturini, F, Garzon, W Q, Ferrer, P, Grinter, D C, Held, G & Syres, K L 2021, ' Near-Ambient Pressure XPS and NEXAFS Study of a Superbasic Ionic Liquid with CO2 ', The Journal of Physical Chemistry C . https://doi.org/10.1021/acs.jpcc.1c05738

In situ photoemission and near edge X-ray absorption fine structure (NEXAFS) techniques have been used to study the interaction of CO2 with an ionic liquid thin film. A thin film of the superbasic ionic liquid (SBIL) trihexyltetradecylphosphonium ben

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4db68611b03744357267639a7c74d8e1
https://doi.org/10.1021/acs.jpcc.1c05738