Zobrazeno 1 - 10
of 43
pro vyhledávání: '"Willy Gombler"'
Autor:
Willy Gombler, Gerd Bollmann
Publikováno v:
Zeitschrift für Naturforschung B. 47:369-372
Trifluoromethanesulfenylfluoride, CF3SF, adds to the carbon-sulfur double bond to form fluorinated compounds containing a trifluoromethyldisulfanyl group. Reactions of CF3SF with CS2,CF2S,CCl2S and (CF3S)2CS are described.
Autor:
Willy Gombler
Publikováno v:
Magnetic Resonance in Chemistry. 29:73-77
77Se–77Se spin-spin coupling constants of unsymmetrically and, for the first time, of symmetrically substituted diselenides have been measured for CF3SeSeCH3, CF3SeSeCF3, CF3SeSeCF2Cl and CF2ClSeSeCF2Cl. A correlation of the 1J(SeSe) values with th
Publikováno v:
Journal of Magnetic Resonance (1969). 89:10-20
113Cd, 19F, and 13C NMR spectroscopic data of adducts of the type (Rf)2Cd·diglyme (Rf = CF3, C2F5, n-C3F7, i-C3F7, C6F6) are reported for solutions in CD3CN. The cadmium-113 shielding is interpreted in terms of Lewis acid-base complex stability; hig
Autor:
Willy Gombler
Publikováno v:
Magnetic Resonance in Chemistry. 28:553-556
Coupling constants, 1J(13C,13C), of compounds containing a CF3 group are reported. The values for the coupling of the CF3 carbon with the neighbouring carbon are exceptionally large. In a series of compounds in which the CF3 group is bonded to an sp3
Publikováno v:
Inorganic Chemistry. 29:2697-2698
Publikováno v:
Journal of Fluorine Chemistry. 54:355
A study of NMR coupling constants, 1J(13C13C), of compounds containing a CF3 group has revealed that the values for the coupling of the CF3 carbon with the neighbouring carbon are exceptionally large [1]. In a series of compounds in which the CF3
Autor:
Willy Gombler
Publikováno v:
Journal of Magnetic Resonance (1969). 53:69-75
The effect of all selenium isotopes on the nuclear shielding of the neighboring 77Se nucleus in CF3SeSeCF3, CH3SeSeCH3, and CF3SeSeCH3 was observed. The detection of this isotope effect helps to prove that two magnetically equivalent selenium atoms a
Autor:
Gerd Bollmann, Willy Gombler
Publikováno v:
Journal of Fluorine Chemistry. 34:475-485
Trifluoromethylsulfenylfluoride, CF 3 SF, adds to the carbon- carbon double bond of olefins to form partially fluorinated thioethers. The reaction of CF 3 SF with CH 3 CHCH 2 gives the two isomers CH 3 CHFCH 2 SCF 3 (85–94 %) and CH 3 CH(SCF 3 )
Publikováno v:
Zeitschrift für Naturforschung B. 38:815-818
The strong influence of a chalcogen atom (O, S, Se) attached to phosphorus on the spin-spin coupling constant 1J(P-15N) in the family of diastereoisomeric 2-|15N] -phenyl-amino-2X(X = O, S, Se)-4-methyl-l,3,2-dioxaphosphorinanes is demonstrated. The
Autor:
Willy Gombler, Gerd Bollmann
Publikováno v:
Journal of Fluorine Chemistry. 37:15-20
Chlorodifluoromethyl(trifluoromethyl)diselenane, CF 3 SeSeCF 2 Cl, has been prepared by the reaction of CF 3 SeCl with Se=CF 2 . CF 3 SeSeCH 3 has been synthesized via a new route from CF 3 SeSeCF 3 and CH 3 SeSeCH 3 . CF 3 SeSeCF 2 Cl is unstable wi