Zobrazeno 1 - 10
of 19
pro vyhledávání: '"William T. Yap"'
Autor:
William T. Yap
Publikováno v:
Journal of Electroanalytical Chemistry. 454:33-38
Analytical expressions were derived for the harmonics of the current response to an ac voltage input, when the rate-determining process is a redox reaction of a couple confined to the electrode surface. Some input/output phase relations such as funct
Publikováno v:
Langmuir. 11:4818-4822
Direct electron transfer to putidaredoxin (Pdx) in solution from bare gold and mercaptoethylamine-modified gold electrodes was studied by cyclic voltammetry. The current response of Pdx at a bare gold electrode was irreversible and highly unstable. T
Autor:
William T. Yap
Publikováno v:
Biophysical Chemistry. 52:125-130
A general equilibrium model for a class of biochemical reactions was formulated, using the formalism of binding polynomials for the evaluations of the various species. Thermodynamic equilibrium constant was obtained from the observed equilibrium tota
Publikováno v:
Biophysical chemistry. 49(2)
Apparent equilibrium constants and calorimetric enthalpies of reaction have been measured for the beta-lactamase catalyzed hydrolysis of penicillin G(aq) and ampicillin(aq) to penicillinoic acid(aq) and to ampicillinoic acid(aq), respectively. High-p
Autor:
Richard A. Durst, William T. Yap
Publikováno v:
Journal of Research of the National Institute of Standards and Technology
Discontinuous Bessel integrals are applied to a boundary value problem related to chronoamperometry, with zero concentration at the disk satisfied on the average and the zero flux at the shroud satisfied approximately only. Current functions are deri
Publikováno v:
Journal of Electroanalytical Chemistry and Interfacial Electrochemistry. 159:287-293
The charge-time relation for double potential-step large-amplitude chronocoulometry was developed for a system with electrodeposition of the product. The model assumes that the concentration of the product near the electrode cannot be larger than the
Autor:
Richard A. Durst, K.A. Bunding, William A. MacCrehan, William T. Yap, Mary Lou Fultz, Elmo A. Blubaugh
Publikováno v:
Clinical Chemistry. 28:1922-1930
The Organic Electrochemistry Group at the National Bureau of Standards is pursuing several avenues of research of potential application to problems of clinical chemists. With one development, electrochemical detectors for liquid chromatography, organ
Autor:
William T. Yap, Richard A. Durst
Publikováno v:
Journal of Electroanalytical Chemistry and Interfacial Electrochemistry. 216:11-19
A finite elements digital simulation of chronoamperometry with polymer-coated electrodes is presented. The model takes account of mass transport by diffusion and migration, and the effects of the uncompensated resistance and capacitance of the system
Publikováno v:
Journal of Electroanalytical Chemistry and Interfacial Electrochemistry. 271:325-329
Cette etude developpe un modele mathematique permettant d'analyser les resultats experimentaux obtenus lors de l'etude par spectroelectrochimie, de reactions electrochimiques mettant en jeu plusieurs etapes de transfert electronique. Ce modele est te
Publikováno v:
Journal of Electroanalytical Chemistry and Interfacial Electrochemistry. 177:77-88
The electrochemical and spectroelectrochemical behavior of N -methyl-4-(5-phenyl-2-oxazolyl)pyridinium p -toluenesulfonate was studied to provide an evaluation of the electrochromic properties of this laser dye. Preliminary cyclic voltammetric experi