Zobrazeno 1 - 10
of 60
pro vyhledávání: '"William L. Earl"'
Publikováno v:
The Journal of Physical Chemistry B. 104:5890-5896
29Si MAS NMR spectra for TS-1, TiMCM-41, and Ti-β, and 31P MAS NMR spectrum for TiAlPO4-11 have been obtained before and after CO treatment that reduces Ti4+ to Ti3+. We have used the large paramag...
Autor:
Ghansham Panjabi, Tanja Pietrass, Kevin C. Ott, Bruce C. Gates, and William L. Earl, Andrea Labouriau, Bryan Enderle
Publikováno v:
Journal of the American Chemical Society. 121:7674-7681
[Ir4(CO)12] and [Ir6(CO)16] were synthesized in the pores of zeolite NaY by reductive carbonylation of sorbed [Ir(CO)2(acac)], and [Rh6(CO)16] was similarly synthesized from [Rh(CO)2(acac)]. The supported metal carbonyl clusters were decarbonylated t
Publikováno v:
The Journal of Physical Chemistry B. 103:4323-4329
One- and two-dimensional NMR spectra of 129Xe sorbed in NaY zeolite at a loading of approximately 1 Xe atom/4 α-cages were obtained as a function of temperature. One-dimensional spectra were measured over the range of 60−300 K, by far the largest
Publikováno v:
The Journal of Physical Chemistry B. 102:2897-2904
We have related the 29Si MAS NMR chemical shifts of titanosilicates and highly siliceous zeolites linearly with structural factors. Good correlations in titanosilicates were obtained using the model proposed by Sherriff et al.,1,2 where the chemical
Autor:
Andrea Labouriau, William L. Earl
Publikováno v:
Chemical Physics Letters. 270:278-284
We report 47Ti and 49Ti NMR spectra of powdered samples of the three common phases of titania, TiO2. The linewidths are dominated by the electric quadrupole interaction. The relative linewidths of the three samples cannot be explained in terms of sim
Publikováno v:
Physical Review B. 54:9952-9959
Nuclear-spin-lattice relaxation time measurements were made on $^{29}\mathrm{Si}$ nuclei in a series of 2:1 natural clay minerals. The magnetization recovery was found to be nonexponential. The nuclear relaxation arises from coupling to fixed paramag
Publikováno v:
Journal of Magnetic Resonance, Series A. 116:139-144
In the design and construction of NMR probes, it is frequently useful to have the tuning elements remote from the NMR coil and sample space. In such cases, a transmission line is an integral part of the resonance circuit. The characteristics of trans
Publikováno v:
Clays and Clay Minerals. 43:697-704
A series of natural clays, including 1:1 layer silicates (serpentines, kaolin minerals), smectites, vermiculite, micas, talc, pyrophyllite, sepiolite, and palygorskite, were studied by “F magic-angle spinning (MAS) nuclear magnetic resonance (NMR)
Publikováno v:
The Journal of Physical Chemistry. 98:4919-4922
Dynamics and structure of tri-n-butyltin fluoride in n-hexane solutions were probed using (tin-119) nuclear magnetic resonance spin relaxation methodologies. Significant relaxation-induced polarization transfer effects were observed and exploited. Th