Zobrazeno 1 - 3
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pro vyhledávání: '"Wilhelmus R M Overbeek"'
Publikováno v:
ChemInform. 23
Publikováno v:
Tetrahedron. 47:9419-9430
The efficient and stereoselective introduction of the 1α-OH function in vitamin D3 is described starting from the known previtamin D3 adduct 6. The sequence involves the stereoselective allylic bromination to 9, followed by substitution with mercuri
Publikováno v:
Tetrahedron. 40:1179-1182
An efficient method for the preparation of crystalline α-hydroxy previtamin D3 is described. Also the stereoselective reduction of 1-keto previtamin 9 is discussed; it was observed that with aluminum hydride 7 is the most abundant product. This stan