Zobrazeno 1 - 7
of 7
pro vyhledávání: '"Wilfried Majenz"'
Publikováno v:
Chemical Physics. 173:525-537
Semiempirical calculations within the CNDO/S framework are used to characterize the nature of the “phantom-singlet” excited state P * (double-bond twisted geometry) of stilbene and stilbenoid donor-acceptor dye systems including the laser dyes DC
Publikováno v:
Pure and Applied Chemistry. 65:1699-1704
Stilbenes undergo multidimensional adiabatic photochemistry in the excited state involving the twist of the central double and of the adjacent single bonds. By bridging the single bonds chemically, dimen- sionality is reduced, and only one product st
Autor:
René Lapouyade, E. Gilabert, Konstantin Czeschka, Wilfried Majenz, Claude Rullière, Wolfgang Rettig
Publikováno v:
ChemInform. 24
Several selectively bridged 4-(dimethylamino)-4'-cyanostilbenes are investigated. All of them show strongly red-shifted fluorescence spectra connected with a considerable dynamical Stokes shift in polar solvents. Bridging, however, photophysics (fluo
Autor:
E. Gilabert, René Lapouyade, Claude Rullière, Wilfried Majenz, Wolfgang Rettig, Konstantin Czeschka
Publikováno v:
The Journal of Physical Chemistry. 96:9643-9650
Several selectively bridged 4-(dimethylamino)-4'-cyanostilbenes are investigated. All of them show strongly red-shifted fluorescence spectra connected with a considerable dynamical Stokes shift in polar solvents. Bridging, however, photophysics (fluo
Publikováno v:
Journal of Photochemistry and Photobiology A: Chemistry. 65:95-110
Examples of adiabatic photoreactions like excited state proton transfer, excimer and twisted intramolecular charge transfer (TICT) state formation are compared, and the most important methods for their investigation and characterization are outlined.
Publikováno v:
Journal of Photochemistry and Photobiology A: Chemistry. 62:415-427
The photophysics of many flexible dye systems can be understood on the basis of adiabatic photoreactions to emissive or nonemissive product states. Nonemissive product states lead to fluorescence quenching and are often the reason for what is convent
Autor:
Wolfgang Rettig, Wilfried Majenz
Publikováno v:
Chemical Physics Letters. 154:335-341
Time-resolved fluorescence studies on 4-dimethylamino-4′-cyano-stilbene (DCS) and on the laser dye DCM in homologous solvent series of differing polarity reveal a strong polarity control of the temperature-dependent nonradiative decay rate k nr . T