Zobrazeno 1 - 10
of 17
pro vyhledávání: '"Werner E. Klotzbücher"'
Autor:
Werner E. Klotzbücher, Richard Goddard, Franz Mark, Maria-Andrea Mroginski, Oliver Heinemann, Tanja Bauschlicher, Peter Hildebrandt, Károly Németh
Publikováno v:
The Journal of Physical Chemistry A. 109:2139-2150
The structure and vibrational spectra of hexamethylpyrromethene (HMPM) have been investigated by X-ray crystallography, IR and Raman spectroscopies, and density functional theory calculations. HMPM crystallizes in the form of dimers, which are held t
Autor:
Klaus Kerpen, and Werner E. Klotzbücher, Kurt Schaffner, Friedrich-Wilhelm Grevels, Ceyhan Kayran and, Richard Goddard and, Bruno Weimann, Saim Özkar
Publikováno v:
Organometallics. 20:4775-4792
Photolysis of M(CO)4(iprop-dab) (1, M = W; 2, M = Mo; iprop-dab = 1,4-diisopropyl-1,4-diazabuta-1,3-diene) in the presence of (E)-cyclooctene (eco) afforded high yields of the unprecedented olefin-substituted derivatives fac-M(CO)3(iprop-dab)(η2-eco
Autor:
Klaus Angermund, Volker Skibbe, Werner E. Klotzbücher, Christian W. Lehmann, Kurt Schaffner, Franz Mark, Carl Krüger, Saim Özkar, Jürgen Jacke, Friedrich-Wilhelm Grevels
Publikováno v:
Organometallics. 18:3278-3293
The photochemical conversion of W(CO)6 (1) into a trans-W(CO)4(η2-olefin)2 complex has been investigated using (E)-cyclooctene (eco) as a model olefin possessing extraordinary coordination properti...
Autor:
Graham Russell, Werner E. Klotzbücher, Kurt Schaffner, and Manuella Viotte, Friedrich-Wilhelm Grevels,†, R. E. D. McClung, Klaus Kerpen
Publikováno v:
Journal of the American Chemical Society. 120:10423-10433
Photochemical experiments with Fe(CO)3(η4-1,5-cyclooctadiene) (1) in a 13CO matrix at 10 K, monitored by means of IR spectroscopy, indicate the generation of stereoselectively labeled Fe(CO)2(13CO)(η4-1,5-cyclooctadiene) (1-1a), with 13CO in the ap
Publikováno v:
The Journal of Physical Chemistry A. 101:4548-4554
Autor:
Werner E. Klotzbücher, Sylvia M. Draper, Mary T. Pryce, Friedrich-W. Grevels, Conor Long, Graham Russell, Ciara J. Breheny
Publikováno v:
Organometallics. 15:3679-3687
The photochemistry of (η6-2,6-X2C5H3N)Cr(CO)3 was investigated both in low-temperature matrices (X = H or (CH3)3Si) and in room-temperature solution (X = H, CH3, or (CH3)3 Si). Room-temperature pho...
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 114:571-576
The photo-induced isomerization of Fe(CO)3[(1,2,5,6-η)-1,5-COD] (1) yields Fe(CO)3[(1,2,3,4-η)-1,3-COD] (2) with a quantum yield of Φ 0.04 ± 0.005 (λexc 405 nm). Photolysis of 1 in low-temperature matrices generates the fragment Fe(CO)2[(1,2,5,6
Autor:
Werner E. Klotzbücher, Kurt Schaffner, Jürgen Jacke, Richard H. Hooker, Antony J. Rest, Friedrich-Wilhelm Grevels
Publikováno v:
Journal of Organometallic Chemistry. 382:201-224
Photolysis of M(CO)4(η4-norbornadiene) group 6 metal complexes (1) in low-temperature matrices involves both loss of CO and cleavage of metal—olefin bonds to an extent depending on the metal and on the excitation wavelength. In inert matrices mer-
Publikováno v:
Mendeleev Communications. 4:5-7
Cocondensation of samarium vapour with inert gases at cryogenic temperatures yields isolated samarium atoms and small clusters, while in complementary depositions with CO and N 2 novel carbonyl and dinitrogen complexes are formed. Surprisingly, ‘na
Publikováno v:
Springer Proceedings in Physics ISBN: 9783642850622
Ru3(CO)12(µ-CO) is shown to be a pivotal transient in.he photofragmention of Ru3(CO)12 in the presence of added CO.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::f3b6f8820309cc140844883f2ac602f6
https://doi.org/10.1007/978-3-642-85060-8_43
https://doi.org/10.1007/978-3-642-85060-8_43