Zobrazeno 1 - 10
of 177
pro vyhledávání: '"Wen Yang. Wen"'
Publikováno v:
Macromolecules. 40:1521-1528
The structural influence on translational diffusion of 2,2,4-trimethylpentane (TMP) through SEBS triblock polymer (poly(styrene)-block -poly(ethene-co-but-1 -ene)-block -poly(styrene)) was studied using pulse field gradient (PFG) NMR coupled with lat
Publikováno v:
Journal of Membrane Science. 269:118-125
Proton and sodium-23 spectra are reported on acid and sodium neutralized forms of the perfluorosulfonate ionomer (Nafion), respectively. This local structural view is compared with pulse field gradient diffusion measurements of water, methanol and di
Publikováno v:
Macromolecules. 38:3754-3764
Diffusion of pentane, cyclohexane, and toluene in nanocomposite films of fumed silica and poly(2,2-bis(trifluoromethyl)-4,5-difluoro-1,3-dioxole-co-tetrafluoroethylene) is observed by pulse field gradient NMR. The apparent diffusion constant determin
Publikováno v:
Macromolecules. 36:4397-4403
Fluorine-19 NMR was used to study the structure and mobility of the perfluorosulfonate ionomer Nafion (Dupont trademark) in the presence of dimethyl methylphosphonate (DMMP). Fluorine- 19 resonances arising from the ionomeric side chain narrowed rapi
Autor:
Ghirmai Meresi, Wen-Yang Wen, A. A. Jones, Jaimie Gosselin, Paul T. Inglefield, Yingzi Wang, David Azar
Publikováno v:
Macromolecules. 34:6680-6683
Pulse field gradient diffusion measurements were made on the decafluoropentane molecule, CF3CHFCHFCF2CF3, in the copolymer of tetrafluoroethylene (TFE) and 2,2-bis(trifluoromethyl)-4,5-difluoro-1,3-dioxole (BDD). The proton spectrum consisted of two
Autor:
Wen-Yang Wen, A. A. Jones, A Tao, Yingzi Wang, Ghirmai Meresi, Athinodoros Bandis, X Gong, Paul T. Inglefield
Publikováno v:
Polymer. 42:6485-6492
Self-diffusion constants for water, ethanol and decafluoropentane were measured in the perfluorosulfonate ionomer NafionR using pulse field gradient proton NMR. Measurements were made as a function of concentration, temperature and diffusion time. Fo
Autor:
Yingzi Wang, Wen-Yang Wen, Athinodoros Bandis, Paul T. Inglefield, Ghirmai Meresi, A. A. Jones
Publikováno v:
Polymer. 42:6153-6160
At magic angle spinning speeds above 5 kHz, two major fluorine-19 resonances can be resolved in the acid form of the perfluorosulfonate ionomer Nafion (DuPont trademark). The larger signal at −120 ppm versus CFCl3 is assigned to the backbone CF2 gr
Publikováno v:
Solid State Nuclear Magnetic Resonance. 12:153-164
The morphology of an ionomeric polymer blend consisting of an amino-silicone copolymer and zinc neutralized sulfonated polystyrene (ZnSPS) has been studied using proton spin diffusion and small angle X-ray scattering (SAXS). The extent of reaction be
Publikováno v:
Macromolecules. 29:2138-2142
A new experimental approach for measuring diffusion coefficients of sorbed gas in polymers has been developed based on a combination of NMR spectroscopy and the use of polymer microspheres. The system chosen to demonstrate the technique is xenon gas
Publikováno v:
Journal of Polymer Science Part B: Polymer Physics. 33:1495-1503
The self-diffusion coefficients of toluene in polyisobutylene (PIB) solutions were determined using the pulsed field gradient nuclear magnetic resonance technique. The volume fraction of toluene in the polymer was varied from 0.045 up to 0.712 and th