Výsledky vyhledávání - "Warren J. Shaw"

A quantitative measure of the ionicity of selected iron hydride species by examination of the deuterium quadrupole coupling constant (DQCC)

Autor: Warren J. Shaw, Leslie D. Field, Guy K. B. Clentsmith

Publikováno v: Journal of Organometallic Chemistry. 692:3042-3047

The ionicity of the metal hydride bonds of a series of iron hydrides supported by multidentate phosphine donors has been determined by means of DQCC measurements of the isotopically labelled hydrides in concentrated solution in toluene.

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::0abffd4c6584fb2b82aa19f5f9b6e775
https://doi.org/10.1016/j.jorganchem.2007.03.024

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Addition of Nitrogen-Containing Heteroallenes to Iron(II)-Hydrides

Autor: and Warren J. Shaw, Leslie D. Field, Peter Turner

Publikováno v: Organometallics. 20:3491-3499

The reactions between cis-Fe(dmpe)2H2 (dmpe = Me2PCH2CH2PMe2) (1) or cis-Fe(PP3)H2 (PP3 = P(CH2CH2PMe2)3) (2) and phenyl isothiocyanate (PhNCS), ethyl isothiocyanate (EtNCS), and phenyl isocyanate (PhNCO) were investigated. PhNCS reacts with 1 to for

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::44cbb8937b00583a7dafc9e142e94407
https://doi.org/10.1021/om0100030

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Insertion of CO2, CS2, and COS into Iron(II)−Hydride Bonds

Autor: Warren J. Shaw, Eric T. Lawrenz, Leslie D. Field, Peter Turner

Publikováno v: Inorganic Chemistry. 39:5632-5638

The reactions between cis-Fe(dmpe)2H2 (dmpe = Me2PCH2CH2PMe2) (1) or cis-Fe(PP3)H2 (PP3 = P(CH2CH2PMe2)3) (2) and carbon dioxide (CO2), carbon disulfide (CS2), and carbonyl sulfide (COS) are investigated. At 300 K, additions of CO2 (1 atm), CS2 (2 eq

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4a5f60d676c87b2fb2d9d0b0deb8c3a2
https://doi.org/10.1021/ic991399z

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Addition of H2 to a cationic iridium(I) complex: a study using parahydrogen NMR

Autor: Simon B. Duckett, Leslie D. Field, Linnea P. Soler, Warren J. Shaw, Barbara A. Messerle

Publikováno v: Journal of the Chemical Society, Dalton Transactions. :2251-2253

Parahydrogen enhanced NMR signals are used to monitor the reaction between the cationic iridium(I) complex [Ir(BPM)(CO)2][BPh4] (BPM = bis(pyrazol-1-yl)methane) and dihydrogen: four major products are formed in a cascade of reactions.

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::7b402aa0136069ce76c8c5057fa44abc
https://doi.org/10.1039/b003987j

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Functionalisation of carbon dioxide by an iron(II) complex

Autor: Leslie D, Field, Warren J, Shaw, Peter, Turner

Publikováno v: Chemical communications (Cambridge, England). (1)

Addition of carbon dioxide to trans-Fe(dmpe)2(SCHNEt)H 2 affords the iminium carboxylate trans-Fe(dmpe)2(SCHN+(Et)CO2-)H 4, which rearranges to the ferracyle cis-Fe(dmpe)2(SCH2N(Et)C(O)O-kappa S,O) 5.

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=pmid________::f91c28f8252f538d0aad3a7036008d02
https://pubmed.ncbi.nlm.nih.gov/12120303

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Functionalisation of carbon dioxide by an iron(ii) complexElectronic supplementary information (ESI) available: experimental section. See http://www.rsc.org/suppdata/cc/b1/b108492e

Autor: Leslie D. Field, Warren J. Shaw, Peter Turner

Publikováno v: Chemical Communications. :46-47

Addition of carbon dioxide to trans-Fe(dmpe)2(SCHNEt)H 2 affords the iminium carboxylate trans-Fe(dmpe)2(SCHN+(Et)CO2−)H 4, which rearranges to the ferracyle cis-Fe(dmpe)2(SCH2N(Et)C(O)O-κS,O) 5.

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::a9b8e1a270ad6763ed587d22d06b5764
https://doi.org/10.1039/b108492e

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