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We report a redox-neutral catalytic coupling of nitroalkanes and unactivated alkenes that proceeds by a directed carbopalladation mechanism. The reaction is uniquely enabled by the combination of PdI2 as the precatalyst and HFIP solvent. Structurally
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::44f6c386f2614578f10beb890a8b4ea6
https://doi.org/10.26434/chemrxiv-2022-1q5dw-v2
https://doi.org/10.26434/chemrxiv-2022-1q5dw-v2