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Cesium Amide‐Catalyzed Selective Deuteration of Benzylic C‐H Bonds with D2 and Application for Tritiation of Pharmaceuticals.

Autor: Du, Hui‐Zhen, Fan, Jun‐Zhen, Wang, Zhong‐Zhen, Strotman, Neil A., Yang, Haifeng, Guan, Bing‐Tao

Publikováno v: Angewandte Chemie International Edition; 2/13/2023, Vol. 62 Issue 8, p1-6, 6p

Cesium Amide-Catalyzed Selective Deuteration of Benzylic C-H Bonds with D 2 and Application for Tritiation of Pharmaceuticals.

Autor: Du HZ; State Key Laboratory and Institute of Elemento-Organic Chemistry, Nankai University, Tianjin, 300071, China., Fan JZ; Department of Chemistry, Fudan University, Shanghai, 200438, China., Wang ZZ; Department of Chemistry, Fudan University, Shanghai, 200438, China., Strotman NA; Process Research & Development, Merck & Co., Inc., Rahway, New Jersey 07065, USA., Yang H; Process Research & Development, Merck & Co., Inc., Rahway, New Jersey 07065, USA., Guan BT; Department of Chemistry, Fudan University, Shanghai, 200438, China.

Publikováno v: Angewandte Chemie (International ed. in English) [Angew Chem Int Ed Engl] 2023 Feb 13; Vol. 62 (8), pp. e202214461. Date of Electronic Publication: 2022 Nov 22.