Zobrazeno 1 - 10
of 652
pro vyhledávání: '"Wacker process"'
Publikováno v:
Organic Letters. 23:6227-6231
An efficient method for the synthesis of 5-vinyl-2-isoxazolines by Pd-catalyzed intramolecular O-allylation of ketoximes has been developed. The reaction involves Pd(0)-catalyzed π-allyl formation via leaving group ionization or Pd(II)-catalyzed all
Autor:
Elena Zhizhina, L. L. Gogin
Publikováno v:
Catalysis in Industry. 13:263-268
Some specific features in the liquid-phase oxidation of alkenes to ketones or aldehydes in the presence of palladium compounds (Wacker oxidation) are discussed. It is shown that selecting the appropriate conditions of the reaction (the effective comp
Publikováno v:
Kataliz v promyshlennosti. 1:67-73
Features of the liquid-phase oxidation of alkenes to ketones or aldehydes in the presence of palladium compounds (Wacker oxidation) are discussed in the review. It is shown that the appropriate reaction conditions, namely, the efficient composition o
Publikováno v:
Organic Letters. 23:6916-6918
The first enantioselective total synthesis of tricyclic diterpenoid callilongisin B, which was isolated from Callicarpa longissima, has been achieved. The synthetic method includes a diastereoselective 1,4-addition and Hosomi-Sakurai allylation follo
Publikováno v:
Advanced Synthesis & Catalysis. 362:4723-4735
Publikováno v:
Journal of Saudi Chemical Society, Vol 24, Iss 9, Pp 663-672 (2020)
Nanoscaled palladium particles supported on graphitic carbon nitride (Pd0/g-C3N4) is prepared to improve the oxygen transfer in Wacker oxidation via chemical reduction method. From the analysis of FT-IR, XRD, SEM, TEM, XPS and ICP, Pd0 particles are
Publikováno v:
Journal of Catalysis. 389:19-28
While acetaldehyde is industrially produced in the Wacker process by homogeneous catalysts, a heterogeneous catalyst is so far elusive due to rapid deactivation stemming from metal sintering and coke formation. This work reports on a highly efficient
Autor:
O. N. Temkin
Publikováno v:
Kinetics and Catalysis. 61:663-720
The results of 60 years' research into the mechanisms of olefin oxidation catalyzed by palladium complexes (Wacker oxidation) are analyzed. The concepts of the mechanisms of related oxidative carboxylations (Moiseev reaction) and alkoxylations are di
Autor:
Takashi Nakanishi, Takeshi Tanaka, Dachao Hong, Jan Labuta, Ashish Bahuguna, Venkata Krishnan, Suneel Kumar, Shinsuke Ishihara, Hiromichi Kataura, Yoshihiro Kon
Publikováno v:
ACS Sensors. 5:1405-1410
Chemiresistive sensors, which are based on semiconducting materials, offer real-time monitoring of environment. However, detection of nonpolar chemical substances is often challenging because of the weakness of the doping effect. Herein, we report a
Publikováno v:
ACS Central Science
ACS Central Science, Vol 6, Iss 4, Pp 507-512 (2020)
ACS Central Science, Vol 6, Iss 4, Pp 507-512 (2020)
Ethylene is a dynamic plant hormone, and its temporal monitoring can be used to glean insight into plant health and status. However, the real-time distributed detection of ethylene at trace levels under ambient conditions remains a challenge. We repo