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Autor:
W.J. Middleton
Publikováno v:
Journal of Fluorine Chemistry. 100:207-216
Fluorine chemist William J. Middleton (Bill) describes his career at DuPont, including some of his discoveries, a few anecdotes and a little of his poetry.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::af2ffd4dc1a2bb43f0bd437495f5815c
https://doi.org/10.1016/s0022-1139(99)00128-1
https://doi.org/10.1016/s0022-1139(99)00128-1
Autor:
Corrie A. Stankiewicz, W.J. Middleton, Jamie M. Roseman, Sean J. Harrison, C. Blair Zartman, Sarah M. Lee, Eamonn P. Morrison
Publikováno v:
Journal of Fluorine Chemistry. 77:65-70
The selective fluorination of compounds containing benzylic hydrogen atoms was accomplished by electrolysis in a mixture of 70% HF and 30% pyridine (Olah's reagent) using a square wave alternating current (1.76–2.75 V, 0.02–0.05 Hz) and Pt electr
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::dbd99393b44ecedbc97bc828a3718b1a
https://doi.org/10.1016/0022-1139(95)03379-3
https://doi.org/10.1016/0022-1139(95)03379-3
Publikováno v:
Microchemical Journal. 48:192-199
An electrochemical microcell that can utilize a 70:30 mixture of HF and pyridine as both the solvent and the supporting electrolyte was constructed and interfaced with a computer for monitoring and control. 4-Nitrotoluene was selectively fluorinated
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::af26182ec665a70f572d14168121236c
https://doi.org/10.1006/mchj.1993.1090
https://doi.org/10.1006/mchj.1993.1090
Autor:
W.J. Middleton, Thomas M. Kirrane
Publikováno v:
Journal of Fluorine Chemistry. 62:289-292
Five examples of 7-amino-4-perfluoroheptylcoumarins ( 3 ), a novel class of perfluorocarbon-solubledyes, have been prepared by the reaction of β-ketoesters containing a perfluoroheptylgroup ( 1a and b ) with 3-aminophenols ( 2a , b and c ). All thes
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::8647822f235f191f55ed826f713e4bd2
https://doi.org/10.1016/s0022-1139(00)80102-5
https://doi.org/10.1016/s0022-1139(00)80102-5
Autor:
S. J. Harrison, W.J. Middleton, E. P. Morrison, C. A. Stankiewicz, S. M. Lee, J. M. Roseman, C. B. Zartman
Publikováno v:
ChemInform. 27
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::27a1147e3a251d3bd3d2edc6b7f92250
https://doi.org/10.1002/chin.199638090
https://doi.org/10.1002/chin.199638090
Publikováno v:
Journal of Fluorine Chemistry. 51:419-431
Twenty-one examples (10a–d, 11a–1 and 12a–e) of a new class of surfactants, the amine(polyfluoroalkoxyacyl)imides, were prepared by the reaction of esters containing polyfluoroalkoxy groups with tertiary alkylaminimides and hydroxyalkylaminimid
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::5e5e4e19c79d5f009bdfcf0f935d327b
https://doi.org/10.1016/s0022-1139(00)80195-5
https://doi.org/10.1016/s0022-1139(00)80195-5
Publikováno v:
Journal of Fluorine Chemistry. 48:63-75
The relative polarity of a number of solvents, including perfluorocarbons, has been determined by measuring the bathochromic shift (as the solvent polarity increases) of the UV-visible λ max of a new class of dyes, the (α-perfluoroheptyl-β,β-dicy
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::2a26f155a8b6b031f88ec0695683cab4
https://doi.org/10.1016/s0022-1139(00)82602-0
https://doi.org/10.1016/s0022-1139(00)82602-0
(α-Perfluoroheptyl-β,β-dicyanovinyl)aminostyrenes: A novel class of perfluorocarbon-soluble dyes [1]
Autor:
Bethany K. Freed, W.J. Middleton
Publikováno v:
Journal of Fluorine Chemistry. 47:219-225
Several examples of (α-perfluoroheptyl-β,β-dicyanovinyl)aminostyrenes ( 3 ), a novel class of perfluorocarbon-soluble dyes, were prepared by the reaction of 2-chloro-1,1-dicyano-2- (perfluoroheptyl)ethylene ( 2 ) with aromatic amines. The ethylene
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::838729a8c279a3663980a9e0141fe216
https://doi.org/10.1016/s0022-1139(00)82374-x
https://doi.org/10.1016/s0022-1139(00)82374-x
Publikováno v:
e-EROS Encyclopedia of Reagents for Organic Synthesis
(R = Me) [59218-87-0] C9H27F2N3SSi (MW 275.55) InChI = 1S/C6H18N3S.C3H9F2Si/c1-7(2)10(8(3)4)9(5)6;1-6(2,3,4)5/h1-6H3;1-3H3/q+1;-1 InChIKey = JMGVTLYEFSBAGJ-UHFFFAOYSA-N (R = Et) [59201-86-4] C15H39F2N3SSi (MW 359.73) InChI = 1S/C12H30N3S.C3H9F2Si/c1-
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::049013bc1592c67015de8ea54d61c4ee
https://doi.org/10.1002/047084289x.rt401.pub2
https://doi.org/10.1002/047084289x.rt401.pub2
