Photochemical intermediates of trans-Rh(CO)L2Cl where L=PMe3, PBu3, and i-Pr2HN and cis-Rh(CO)2(i-Pr2HN)Cl in frozen organic glasses

Autor: J. Timothy Bays, James A. Franz, W.Bruce Scallorn, Callie A Weiss, Rinaldo Poli, John C. Linehan, Thomas E. Bitterwolf

Publikováno v: Journal of Organometallic Chemistry
Journal of Organometallic Chemistry, Elsevier, 2002, 652 (1-2), pp.95-104. ⟨10.1016/S0022-328X(02)01312-8⟩

International audience; The Nujol glass matrix photolyses of Rh(CO)(PMe3)2Cl (1), Rh(CO)(PBu3)2Cl (2), Rh(CO)2(i-Pr2HN)Cl (3), and Rh(CO)(i-Pr2HN)2Cl (4), have been examined. Phototolysis of 1 (λirr>400 nm) and 2 (350

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f6a07ff83d76899bf058d52c7abcd821
https://doi.org/10.1016/s0022-328x(02)01312-8

Synthesis, Nujol matrix and solution photochemistry of M(CO)2[η5,η3-C5H4–C(CH3)2–C5H6] (where M=Cr or Mo): molecular structures of Cr(CO)2[η5,η3-C5H4–C(CH3)2–C5H6], Mo(CO)2[η5,η3-C5H4–C(CH3)2–C5H6], and Mo(CO)[P(C6H5)3][η5,η3-C5H4–C(CH3)2–C5H6]

Autor: Joyce E. Shade, Louise M. Liable-Sands, J. Timothy Bays, Callie A Weiss, W.Bruce Scallorn, Thomas E. Bitterwolf, Abdelhimed A. Saygh, Arnold L. Rheingold

Publikováno v: Journal of Organometallic Chemistry. 583:152-161

Reaction of chromium or molybdenum carbonyl with 2,2-bis(cyclopentadienyl)propane yields mixtures of products including M2(CO)6[η5,η5-C5H4–C(CH3)2–C5H4], M2(CO)6[η5-C5H4–C(CH3)2–C5H4]2, and the title compounds, M(CO)2[η5,η3-C5H4–C(CH3)

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::faae2fe2a7de1813066df3a7082bd078
https://doi.org/10.1016/s0022-328x(99)00118-7