Zobrazeno 1 - 10
of 228
pro vyhledávání: '"W. Weltner"'
Publikováno v:
The Journal of Physical Chemistry A. 105:11018-11025
After preliminary studies of CH4 in solid argon and hydrogen, the infrared absorption spectra of matrix-isolated SiH4 and SiD4 in solid argon, hydrogen, and deuterium at 2−4 K were measured. The tw...
Autor:
W. Weltner, John T. Graham
Publikováno v:
The Journal of Physical Chemistry A. 104:9302-9306
Autor:
John T. Graham, W. Weltner
Publikováno v:
The Journal of Physical Chemistry A. 103:4594-4597
Benzene (C6H6, C6D6, 13C6H6) and naphthalene (C10H8, C10D8) molecules were trapped in solid normal hydrogen, normal deuterium, and for comparison, neon and argon. The triplet states of the aromatic...
Publikováno v:
The Journal of Physical Chemistry A. 103:1025-1028
Electron-spin-resonance (ESR) spectroscopy has been applied to vanadium, niobium (and tantalum) complexes with N2 and CO in the corresponding pure solid matrixes at 4 K. Except for V(CO)6, none has previously been studied by ESR. For these d,5 S = 1/
Publikováno v:
The Journal of Chemical Physics. 107:4756-4759
BH4, with isotopic substitution, has been prepared and trapped in solid H2, D2, HD by laser vaporization of boron and subsequent reaction with the matrix gas. The results confirm the C2v structure of the molecule and generally support the results of
Publikováno v:
The Journal of Physical Chemistry A. 101:2917-2920
Publikováno v:
The Journal of Chemical Physics. 106:2583-2588
Laser-vaporized platinum metal, trapped in solid Ne, Ar, Kr, Xe (and Ar, Kr mixture) produced a progression of absorption bands with a spacing of ∼200 cm−1 beginning at 1942 cm−1 in Ne and shifting successively to 1579 cm−1 in Xe. In contrast
Publikováno v:
The Journal of Chemical Physics. 106:2055-2059
Two vibronic transitions, 2Δ3/2(v=0)←2Δ5/2(v″=0) and 2Π3/2(v=0)←2Δ5/2(v″=0) at 923 and 2560 cm−1, respectively, were observed for NiH in solid argon (and krypton) at 4 K. These Ω=3/2←Ω=5/2 transitions were shifted and broadened by m
Publikováno v:
The Journal of Chemical Physics. 103:2762-2765
Electron‐spin‐resonance (ESR) spectroscopy of these molecules in argon matrices at 2 K reveals that each has a 4∑ ground electronic state, the same as TiV, also containing 9 valence (s+d) electrons. TiTa and ZrTa were not observed. An analogy c
Publikováno v:
The Journal of Physical Chemistry. 99:6277-6285
$^{a}$W. Weltner, Jr., R.J. Van Zee, and S. Li. J. Phys. Chem. 99, 6277 (1995). $^{b}$Y.M. Hamrick and W. Weltner, Jr.,. J. Chem. Phys. 94 3371 (1991). $^{c}$R.J. Van Zee and W. Weltner, Jr., Chem. Phys. Lett (accepted). $^{d}$S. Li, H.A. Weimer, R.J